Silver catalyst and its preparation

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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549534, B01J 2104, B01J 2350

Patent

active

047404930

ABSTRACT:
A silver catalyst for the direct oxidation of ethylene with oxygen to give ethylene oxide is applied on a porous carrier and essentially consists of .alpha.-alumina and contains certain amounts of soluble calcium, aluminum, potassium and sodium salts. The carrier has a BET surface area of from 0.2 to 0.8 m.sup.2 /g, a pore volume of not less than 0.5 ml/g, the pores being equally accessible to cold and warm water, and a bulk density of less than 650 kg/m.sup.3, and has a shape which, in the reactor, provides a geometric surface area of not less than 600 m.sup.2 /m.sup.3, on which more than 13% by weight of silver are applied as the active component, more than 110 kg of silver being available per m.sup.3 of reactor.

REFERENCES:
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patent: 3423328 (1969-01-01), Keith et al.
patent: 3962136 (1976-06-01), Nielsen et al.
patent: 4010115 (1977-03-01), Nielsen et al.
patent: 4455392 (1984-06-01), Warner et al.
patent: 4458032 (1984-07-01), Rebsdat et al.

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