Siloxane-containing polymers and contact lenses therefrom

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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556453, C08F 3008, C08F13008, C08F23008

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active

044502648

ABSTRACT:
There are prepared acrylates and methacrylates of the formula ##STR1## wherein R is hydrogen or methyl, y is 1 to 3, z is 0 to 2, y+z is 3, and wherein A is the unit (I) ##STR2## wherein x is 0 to 4, or the unit (II) ##STR3## with the proviso that when A is unit II, then z is zero. The novel siloxane compounds can be copolymerized with (1) a monoethylenically unsaturated monomer having a polymerizable carbon-to-carbon double bond, and (2) a cross-linking agent having at least two polymerizable, ethylenically unsaturated bonds. The resulting copolymers have high oxygen permeability and proper hydrophilic property. They can be made substantially water non-absorptive. Contact lenses fabricated from such copolymers can, if desired, be worn continuously for long periods of time.

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patent: 4139513 (1979-05-01), Tanaka et al.
patent: 4153641 (1979-05-01), Deickert et al.
patent: 4182822 (1980-01-01), Chang
patent: 4303772 (1981-12-01), Novicky

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