Silicone surfactants for rigid polyurethane foam made with third

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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516 8, 521131, C08J 914

Patent

active

058831428

ABSTRACT:
A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing as a blowing agent a C1-C4 HFC or HCFC, preferably HFC-245fa, and as the silicone surfactant a polyether-polysiloxane coploymer having a total surfactant molecular weight of 12,000 to 100,000 g/mole, a wt % siloxane in the surfactant of 10 to 40 wt %, a molecular weight of the polyether portion of 1200 to 6,000 g/mole, and a wt % of ethylene oxide in the polyether portion of 30-100 wt %.

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Barthelemy, P. P., and Leroy, A., "Latest Results in the Development of Next Generation HFC Blowing Agents" Polyurethane 1995, Sep. 26-29, 1995, pp. 26-33.
Bogdan, M. C., Williams, D. J., et al. "Status Report on the Development of HFC-245fa as a Blowing Agent" Polyurethane EXPO 1996 pp. 394-403.
Bodnar, T. W., Koch, J. J.; and Thornsberry, J. D., "New Surfactant Technology for HCFC-123 and HCFC-141b Blown Rigid Foam Systems", Polyurethane World Congress 1991, pp. 24-26.

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