Silicone resins having good thermal stability

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 18S, 260 37SB, 260 465R, 260824R, 260825, C08K 501

Patent

active

040850846

ABSTRACT:
A process for producing a silicone resin composed solely of difunctional siloxy units comprising hydrolyzing a diorganodihalosilane in a heterogeneous hydrolysis mixture having therein water, acetone, a water-immiscible organic solvent and optionally, an alcohol; wherein said hydrolysis must take place within ten minutes, and separating the water layer from the water-immiscible solvent silicone resin layer.
The silicone resin is further purified and bodied in subsequent process steps. There is also provided by the present invention a silicone resin mixture composed of the above difunctional silicone resin and a silicone resin composed of trifunctional siloxy units and difunctional siloxy units which silicone resin mixture has good thermal stability at temperatures up to 700.degree. F.

REFERENCES:
patent: 3375223 (1968-03-01), Merrill
patent: 3489782 (1970-01-01), Pruvost et al.
patent: 3865766 (1975-02-01), Merrill

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