Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1977-02-16
1978-09-12
Shaver, Paul F.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
2604488R, 528 14, C08L 0000
Patent
active
041136900
ABSTRACT:
Alpha-alkoxy-omega-siloxanols, R'O(R.sub.2 SiO).sub.x H, are produced by contacting cyclic siloxanes with alcohols under mild conditions. For example, hexamethylcyclotrisiloxane heated at reflux in methanol for four hours gives 5-methyoxyhexamethyltrisiloxan-1-ol in high yield. The reaction proceeds more rapidly in the presence of weak acids or bases. The products are useful as coupling agents, as antistructure agents and filler-treating agents for silicone elastomers.
REFERENCES:
patent: 3417047 (1968-12-01), Golitz et al.
Shaver Paul F.
SWS Silicones Corporation
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