Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing
Patent
1998-11-09
2000-05-23
Hiteshew, Felisa
Chemistry of inorganic compounds
Silicon or compound thereof
Oxygen containing
117 13, C01B 3326
Patent
active
060663065
ABSTRACT:
In a method for producing a silicon single crystal wafer, a silicon single crystal is grown in accordance with the Czochralski method such that the F/G value becomes 0.112-0.142 mm.sup.2 /.degree.C.multidot.min at the center of the crystal, where F is a pulling rate (mm/min) of the single crystal, and G is an average intra-crystal temperature gradient (.degree.C/mm) along the pulling direction within a temperature range of the melting point of silicon to 1400.degree. C. Additionally, the single crystal is pulled such that the interstitial oxygen concentration becomes less than 24 ppma , or the time required to pass through a temperature zone of 1050-850.degree. C. within the crystal is controlled to become 140 minutes or less. The method allows production of silicon single crystal wafers in which neither FPDs nor L/D defects exist on the wafer surface, which therefore has an extremely low defect density, and whose entire surface is usable.
REFERENCES:
Yamashita, et al. "Effects of Thermal History on OSF Formation in CZ Silicon Crystals," Electrochemical Society Extended Abstracts, vol., 89-1, May 1989, pp. 346-347.
Dupret, et al. "Global Modelling of Heat Transfer in Crystal Growth Furnaces," Int. J. Heat Mass Transfer, vol. 33, No. 9, pp. 1849-1871, 1990.
Sadamitsu, et al. "Dependence of the Grown-in Defect Distribution on Growth Rates in Czochralski Silicon," Jpn. J. Appl. Phys. vol. 32 (1993) pp. 3675-3681, Part 1, No. 9A, Sep. 1993.
Iida Makoto
Iino Eiichi
Kimura Masanori
Muraoka Shozo
Hiteshew Felisa
Shin-Etsu Handotai & Co., Ltd.
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