Compositions: ceramic – Ceramic compositions – Refractory
Patent
1994-03-31
1995-01-24
Group, Karl
Compositions: ceramic
Ceramic compositions
Refractory
501 98, C04B 3558
Patent
active
053842928
ABSTRACT:
A silicon nitride composite sintered which comprises crystal grains of silicon nitride and/or sialon having an average minor axis length of 0.05 to 3 .mu.m and an aspect ratio of 10 or less and foreign particles dispersed in the crystal grains and/or the grain boundary phase, said particles having a thermal expansion coefficient of 5.times.10.sup.-6 /.degree.C. or more and an average particle size of 1 to 500 nm. The sintered body is produced by wet mixing silicon nitride powder, at least two sintering aids selected from among Y.sub.2 O.sub.3, Al.sub.2 O.sub.3, AlN and MgO and at least one compound selected from among the oxides, nitrides, carbides and silicides of the elements, excluding Si and C, of the groups IIa, IIIa, IVa, Va, VIa, IIb, IIIb and IVb of the Periodic Table to form a molding; and heat treating under the specified conditions. The sintered body can also be obtained by coating the surfaces of silicon nitride crystal grains with an organometallic compound convertible to the above foreign particles, heat treating and sintering with the sintering aid.
REFERENCES:
patent: 4923829 (1990-05-01), Yasutomi et al.
patent: 5045513 (1991-09-01), Mizuno et al.
patent: 5178647 (1993-01-01), Komatsu et al.
patent: 5214009 (1993-05-01), Komatsu et al.
patent: 5316856 (1994-05-01), Suzuki et al.
Komura Osamu
Matsui Jin-Joo
Miyake Masaya
Yamakawa Akira
Bierman Jordan B.
Group Karl
Sumitomo Electric Industries Ltd.
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