Silicon carboxide composite reinforced with ceramic fibers havin

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Rod – strand – filament or fiber

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428373, 428375, 428384, 428698, 501 11, 501 35, 501 94, 501905, 4272551, 65 171, C03B 2900, B32B 900

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059551941

ABSTRACT:
An improved fiber reinforced glass composite includes a boron-containing refractory fiber having its surface enriched with boron nitride in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane or non-cyclic siloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The boron nitride-containing fiber is the product of treating the boron-containing fiber with ammonia at a temperature between about 1100.degree. C. and 1250.degree. C. Fibrous failure rather than brittle failure under stress can be obtained.

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