Silicate superionic conductors and method of making same

Compositions: ceramic – Ceramic compositions – Yttrium – lanthanide – actinide – or transactinide containing

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106 74, 423263, 423332, 429 33, 429193, C04B 3516, C04B 3550

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active

046578790

ABSTRACT:
The spray-drying of a feed liquid mixture containing dissolved feed elements is used to produce precursor powders of Na.sup.+ -super conducting sodium gadolinium silicate (Na.sub.5 GdSi.sub.4 O.sub.12), (NGS), and sodium yttrium silicate (Na.sub.5 YSi.sub.4 O.sub.12), NYS. Using these powders, very dense (>97% theoretical) solids are obtained on sintering. The resistivities of the NGS and NYS polycrystalline ceramics are 5 and 7 (.OMEGA. cm) respectively at 300.degree. C. and are dependent on the f(NGS) or f(NYS) values. In the case of NYS, the resistivity/f(NYS) relationship takes the form ##EQU1## indicative of resistive and conductive phases mixed more in parallel than in series.

REFERENCES:
patent: 4097345 (1978-06-01), Shannon

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