Silicate-based green phosphors

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

Reexamination Certificate

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C252S30160F, C252S30140H, C252S30140P, C252S30160P, C257S098000, C313S503000, C313S582000, C313S584000, C313S486000

Reexamination Certificate

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07575697

ABSTRACT:
Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1cation replaces Sr; the A2cation replaces Si, and the A3anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

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