Silica supported transition metal catalyst

Details Silica supported transition metal catalyst Silica supported transition metal catalyst

1992-03-20

1993-07-27

Garvin, Patrick P.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526124, 526129, 526151, 502113, 502115, C08F 4685, C08F 4646

Patent

active

052311511

ABSTRACT:
A transition metal containing catalyst useful for the polymerization of .alpha.-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m.sup.2 /g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state.

REFERENCES:
patent: 3113115 (1963-12-01), Ziegler et al.
patent: 3257332 (1966-06-01), Ziegler et al.
patent: 3645992 (1972-02-01), Elston
patent: 3787384 (1974-01-01), Stevens et al.
patent: 3876565 (1975-04-01), Takashima et al.
patent: 4100238 (1978-07-01), Shinomura
patent: 4148754 (1979-04-01), Strobel et al.
patent: 4173547 (1979-11-01), Graff
patent: 4198038 (1980-04-01), Quinter
patent: 4205021 (1980-05-01), Morita et al.
patent: 4374753 (1983-02-01), Pullukat et al.
patent: 4426316 (1984-01-01), Gessell
patent: 4446288 (1984-05-01), Hoff
patent: 4451574 (1984-05-01), Johnson
patent: 4472328 (1984-09-01), Sugimoto et al.
patent: 4478988 (1984-10-01), Pullukat et al.
patent: 4481301 (1984-11-01), Nowlin et al.
patent: 4481342 (1984-11-01), Invernizzi et al.
patent: 4522987 (1985-06-01), Hogan et al.
patent: 4526943 (1985-07-01), Fuentes, Jr. et al.
patent: 4544647 (1985-10-01), Fuentes, Jr. et al.
patent: 4558024 (1985-12-01), Best
patent: 4593009 (1986-06-01), Nowlin
patent: 4612300 (1986-09-01), Coleman, III
patent: 4661465 (1987-04-01), Fuentes, Jr. et al.
patent: 4672096 (1987-06-01), Nowlin
patent: 4677087 (1987-06-01), Lo et al.
patent: 4783512 (1988-11-01), Gessell
patent: 4829096 (1989-05-01), Kitamura et al.
patent: 4833111 (1989-05-01), Nowlin
patent: 4849267 (1989-07-01), Ward et al.
patent: 4849389 (1989-07-01), Nowlin
patent: 4849390 (1989-07-01), Sano et al.
patent: 4878974 (1989-11-01), Kagawa
patent: 4891173 (1990-01-01), Saitoh et al.
patent: 4894265 (1990-01-01), Chang et al.
patent: 4910272 (1990-03-01), Marchand et al.
patent: 4918038 (1990-04-01), Samuels et al.
patent: 4963426 (1990-10-01), Nishimoto et al.
Polym. Engng. Sci 25, No. 5, pp. 279.varies.283, Mid-Apr., 1985.
Derwent 83-786729/41 (1983).
Derwent 88-297390/42 (1988).
Derwent 89-071723/10 (1989).
Derwent 89-071724/10 (1989).
CA 72(14):67859s (1969).
CA 75(2):6984u (1971).
CA 90(24):188237t (1979).
CA 96(26):219004v (1982).
CA 98(12):90771c (1982).
CA 98(16):127414s (1983).
CA 98(20):161832m (1983).
CA 99(18):141197a (1983).
CA 100(8):52814w (1983).
CA 102(2):7859v (1984).
CA 103(26):216517s (1985).
CA 104(12):90059u (1985).
CA 105(4):25218b (1986).
CA 105(4):25545f (1986).
CA 108(14):113732g (1987).
CA 110(6):40368x (1988).
CA 110(24):214474w (1989).
CA 111(10):79577k (1989).
CA 111(10):79690s (1989).
CA 111(20):175415b (1989).
CA 111(20):175416c (1989).
Kuhre, C. J., M. Wales and M. E. Doyle in "Crystallization-Modified Polypropylene," SPE Journal, pp. 1113-1119, Oct. 1964.
Narh, K., J. Odell, A. Keller and G. Fraser in "The effect of nucleation density on the kinetics of crystallization and on the resulting structure and thermal properties of polymers crystallized during cooling," J. Mat. Sci. pp. 2001-2009(1990).
Dohrer, K., L. Hazlitt and N. Whiteman in "Short Chain Branching Distribution of ULDPE," J. Plastic Film and Sheeting, vol. 4, pp. 214-226, Jul. 1988.
Eur. Plast. News 14, No. 5, "Cast Film Palletwrap Selection" p. 47, May 1987.
Poliplasti Plast. Rinf. 31, Nos. 308/9, "Linear Low Density Polyethylene in Extrusion and Moulding," pp. 24-39, Jul./Aug. 1983.
Poliplasti Plast. Rinf. 31, No. 306, "Advantages and Disadvantages of Blends of Conventional and Linear Low Density Polyethylenes" pp. 45-55, May 1983.
Journal of Applied Polymer Science: Applied Polymer Symposium 45, pp. 25-37 (1990).

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