Silane-grafted materials for solid and foam applications

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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521 79, 521 82, 525 63, 525 64, 525 70, 525191, 264 457, 264 459, 264232, 264239, C08F21000

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active

058831444

ABSTRACT:
New cross-linked polymeric foam compositions, and methods for making the same, are provided. The new compositions utilize novel cross-linked polyolefin copolymers and show improvements in strength, toughness, flexibility, heat resistance and heat-sealing temperature ranges as compared to conventional low density polyethylene compositions. The new compositions also show processing improvements over linear low density polyethylene. The novel polyolefins, which are essentially linear, comprise ethylene polymerized with at least one alpha-unsaturated C3 to C20 olefinic comonomer, and optionally at least one C3 to C20 polyene, and exhibit, in an uncross-linked sense, a resin density in the range of about 0.86 g/cm.sup.3 to about 0.96 g/cm.sup.3, a melt index in the range of about 0.5 dg/min to about 100 dg/min, a molecular weight distribution in the range of from about 1.5 to about 3.5, and a composition distribution breadth index greater than about 45 percent. The polyolefins are silane-grafted to enhance the physical properties and processability of the resins. Slow silane-grafted materials exhibit enhanced physical and processing properties.

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