Silacyclohexane carbaldehyde compounds and processes for prepari

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

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25229966, 359103, 556406, C09K 1930, G02F 113, C07F 708

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active

055274900

ABSTRACT:
A silacyclohexane carbaldehyde compound of the following formula (I) ##STR1## wherein Ar represents a phenyl group or a tolyl group, and R represents a phenyl group, a tolyl group, a linear alkyl group, a mono or difluoroalkyl group, a branched alkyl group, an alkoxyalkyl group or an alkenyl group. Processes for preparing a silacyclohexane-based liquid crystal compound of the following formula (II) or (III) from the silacyclohexane carbaldehyde are also described ##STR2## wherein X represents CN, F, Cl, CF.sub.3, CClF.sub.2, CHClF, OCF.sub.3, OCClF.sub.2, OCHF.sub.2, OCHClF, (O).sub.m CT=CX.sub.1 X.sub.2, O(CH.sub.2).sub.r (CF.sub.2).sub.s X.sub.3, R or OR wherein m is a value of 0 or 1, T and X.sub.1 independently represent H, F or Cl, X.sub.2 represents F or Cl, r and s are, respectively, a value of 0, 1 or 2 provided that r+s=2, 3 or 4, X.sub.3 represents H, F or Cl, and R has the same meaning as defined before, Y and Z independently represent a halogen or a methyl group, i and j are independently a value of 0, 1 or 2.

REFERENCES:
patent: 4973723 (1990-11-01), Cawthon et al.
patent: 5454977 (1995-10-01), Shimizu et al.
Washburn, S. S. et al., "Acetolysis of 4,4-disubstituted 4-silacyclohexyl tosylates: Effect of remote silicon substitution on organic reactivity." Journal of Organometallic Chemistry, vol. 133, 1977, pp. 7-17.

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