Shutdown process for olefin polymerization reactor

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585502, 585520, 585527, 585950, C07C 202

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active

059327782

ABSTRACT:
A method is provided which can be used to quickly and easily take a fixed-bed of solid acid olefin polymerization catalyst out of service without causing any significant catalyst deactivation. The method involves substituting a substantially olefin-free hydrocarbon fluid for at least a portion of the olefin-containing feedstock to the polymerization process, wherein the substantially olefin-free hydrocarbon fluid boils within the range from about 20.degree. to about 250.degree. C. and contains at least about 5 vol. % aromatics.

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