Shunt recognition in lithium batteries

Electricity: battery or capacitor charging or discharging – Serially connected batteries or cells – With discharge of cells or batteries

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320 39, 320 31, 320 21, H01M 1044, H02J 704

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057291160

ABSTRACT:
An apparatus and method of recognizing a shunt caused by formation of dendrites in a rechargeable lithium battery which comprises charging the battery with a charging current, sampling the charging current voltage of the battery at pre-determined time intervals in order to identify one or more point indicating onset of shunting, and terminating charging if the shunt or dendrite is indicated. If a shunt is not recognized charging is continued. Dendrite formation or the beginning of shunting due to such formation is indicated by any one of the following conditions: a negative gradient in sampled voltage values; a negative gradient in sampled steady open circuit values; and a negative gradient in the chemical polarization voltage values which may be calculated by sampling both the open circuit voltage soon after current interruption and steady open circuit voltages during a plurality of currentless phases.

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