Shaped polyethylene articles of intermediate molecular weight an

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – Shaping by extrusion

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264 461, 264203, 264204, 2642107, 2642108, D01D 508

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active

046631011

ABSTRACT:
Solutions of intermediate molecular weight polymers from about 200,000 to about 4,000,000, such as polyethylene, in a relatively non-volatile solvent are extruded through an aperture at constant concentration and thereafter stretched at a ratio of at least about 3:1 prior to cooling to form a first gel. The first gels are extracted with a volatile solvent to form a second gel, and the second gel is dried to form a low porosity xerogel. Stretching occurs with any one or more of the first gel, second gel or xerogel. The polyethylene products produced by our process include products having a molecular weight between about 200,000 and about 4,000,000 a tenacity of at least about 13 grams/denier, a modulus of at least about 350 gram/denier, a porosity of less than 10% by volume, a crystalline orientation function of at least about 0.95, and a main melting temperature of at least about 140.degree. C.

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patent: 3846404 (1974-11-01), Nichols
patent: 4455273 (1984-06-01), Harpell et al.
patent: 4530809 (1985-07-01), Shindo et al.
patent: 4536536 (1985-08-01), Kavesh et al.
patent: 4599267 (1986-07-01), Kwon et al.

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