Shape selective reactions with group VIIA metal modified zeolite

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585470, 585474, 585475, 252455Z, C07C 352, C07C 362, B01J 2936

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042752566

ABSTRACT:
A process for the conversion of aromatic compounds to dialkylbenzene compounds rich in the 1,4-dialkylbenzene isomer. The reaction is carried out in the presence of a particular type of zeolite catalyst having a silica to alumina mole ratio of at least 12 and a constraint index of about 1-12, said catalyst having been modified by treatment with compounds of manganese and/or rhenium, and optionally phosphorus, to deposit a minor proportion of such elements on the zeolite.

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