Shape selective reactions utilizing zeolites modified with Group

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585466, 585470, 585474, 585475, C07C 268, C07C 522, C07C 552

Patent

active

043026214

ABSTRACT:
A process for the conversion of aromatic compounds to dialkylbenzene compounds rich in the 1,4-dialkylbenzene isomer. The reaction is carried out in the presence of a particular type of zeolite catalyst having a silica to alumina mole ratio of at least 12 and a constraint index of about 1-12, said catalyst having been modified by treatment with compounds of Group V A of the Periodic Chart (V, Nb and Ta), and optionally phosphorus, to deposit a minor proportion of such elements on the zeolite.

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