Shape memory polymers based on semicrystalline thermoplastic...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C524S404000, C524S424000, C524S428000, C524S433000, C524S434000, C524S437000, C524S442000, C524S444000, C524S445000, C525S424000, C528S073000, C528S074000

Reexamination Certificate

active

07091297

ABSTRACT:
Thermoplastic polyurethanes having an alternating sequence of hard and soft segments in which a nanostructured polyhedral oligomeric silsesquioxane diol is used as a chain extender to form a crystalline hard segment constituting SMPs. The polyurethanes are formed by reacting a polyol, a chain extender dihydroxyl-terminated POSS and a diisocyanate. The polyurethanes have multiple applications including for example, implants for human health care, drug delivery matrices, superabsorbant hydrogels, coatings, adhesives, temperature and moisture sensors, etc.

REFERENCES:
patent: 3383336 (1968-05-01), Kuyama et al.
patent: 3459725 (1969-08-01), Natta et al.
patent: 3563973 (1971-02-01), Arditti et al.
patent: 4612241 (1986-09-01), Howard, Jr.
patent: 5145935 (1992-09-01), Hayashi
patent: 5147385 (1992-09-01), Beck et al.
patent: 5163952 (1992-11-01), Froix
patent: 5189110 (1993-02-01), Ikematu et al.
patent: 5258020 (1993-11-01), Froix
patent: 5282854 (1994-02-01), Yagi et al.
patent: 5395882 (1995-03-01), Siol et al.
patent: 5506300 (1996-04-01), Ward et al.
patent: 5607467 (1997-03-01), Froix
patent: 5665822 (1997-09-01), Bitler et al.
patent: 5674242 (1997-10-01), Phan et al.
patent: 5769883 (1998-06-01), Buscemi et al.
patent: 5880240 (1999-03-01), Tsuno
patent: 5889118 (1999-03-01), Delgado et al.
patent: 5908918 (1999-06-01), Chen et al.
patent: 5910357 (1999-06-01), Hachisuka et al.
patent: 5954744 (1999-09-01), Phan et al.
patent: 5955559 (1999-09-01), Handlin et al.
patent: 5964744 (1999-10-01), Balbierz et al.
patent: 6024764 (2000-02-01), Schroeppel
patent: 6086204 (2000-07-01), Magnante
patent: 6156842 (2000-12-01), Hoenig et al.
patent: 6160084 (2000-12-01), Langer et al.
patent: 6217609 (2001-04-01), Haverkost
patent: 6248129 (2001-06-01), Froix
patent: 6368346 (2002-04-01), Jadhav
patent: 6388043 (2002-05-01), Langer et al.
patent: 6395038 (2002-05-01), Schroeppel
patent: 6530950 (2003-03-01), Alvarado et al.
patent: 6538089 (2003-03-01), Samra et al.
patent: 6679605 (2004-01-01), Zhou et al.
patent: 6720402 (2004-04-01), Langer et al.
patent: 6852825 (2005-02-01), Lendlein et al.
patent: 6858680 (2005-02-01), Gunatillake et al.
patent: 2002/0007222 (2002-01-01), Desai
patent: 2002/0015519 (2002-02-01), Tokas et al.
patent: 2002/0137864 (2002-09-01), Tong
patent: 2003/0060793 (2003-03-01), Topolkaraev et al.
patent: 2003/0191276 (2003-10-01), Lendlein et al.
patent: 2004/0014929 (2004-01-01), Lendlein et al.
patent: 2004/0015187 (2004-01-01), Lendlein et al.
patent: 2004/0015261 (2004-01-01), Hofmann et al.
patent: 2004/0024143 (2004-02-01), Lendlein et al.
patent: 2004/0030062 (2004-02-01), Mather et al.
patent: 0 343 442 (1989-05-01), None
patent: 0 368 274 (1989-11-01), None
patent: 0 385 443 (1990-02-01), None
patent: 0 422 693 (1991-02-01), None
patent: 0 422 693 (1991-04-01), None
patent: 1 000 958 (1998-11-01), None
patent: WO 94/14890 (1994-07-01), None
patent: WO 95/26762 (1995-10-01), None
patent: WO 99/42147 (1999-08-01), None
patent: WO 99 42528 (1999-08-01), None
patent: WO 99/46327 (1999-09-01), None
patent: WO 00/10485 (2000-03-01), None
patent: WO 00/71554 (2000-11-01), None
patent: WO 01/07499 (2001-02-01), None
patent: WO 01/10871 (2001-02-01), None
patent: WO 01/91822 (2001-12-01), None
patent: WO 02/39875 (2002-05-01), None
patent: WO 02/059170 (2002-08-01), None
patent: WO 02/083786 (2002-10-01), None
patent: WO 03/035743 (2003-05-01), None
patent: WO 03/084490 (2003-10-01), None
patent: WO 03/084491 (2003-10-01), None
patent: WO 03/088818 (2003-10-01), None
patent: WO 2003/093341 (2003-11-01), None
patent: WO 2004/006885 (2004-01-01), None
patent: WO 2004/011525 (2004-02-01), None
patent: WO 2004/032799 (2004-04-01), None
patent: WO 2004/033515 (2004-04-01), None
patent: WO 2004/033539 (2004-04-01), None
patent: WO 2004/033553 (2004-04-01), None
patent: WO 2005/009523 (2005-02-01), None
patent: WO 2005/070988 (2005-08-01), None
Fu et al., “Structural Development During Deformation of Polyurethane Containing Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules”,Polymer, Vo. 42, 2001, pp. 599-611.
JP 02255830 Abstract Only; Oct. 16, 1990 (1 page).
JP 02274526 Abstract Only; Nov. 8; 1990 (1 page).
JP 11154420 Abstract Only; Jun. 8, 1999 (1 page).
JP 11302493 Abstract Only; Nov. 2, 1999 (1 page).
JP 2232212 Abstract Only; Sep. 14, 1990 (1 page).
JP 2258817 Abstract Only; Oct. 19, 1990 (1 page).
JP 3068610 Abstract Only; Mar. 25, 1991 (1 page).
JP 3068611 Abstract Only; Mar. 25, 1991 (1 page).
JP 4100831 Abstract Only; Apr. 2, 1992 (1 page).
JP 62192440 Abstract Only; Aug. 24, 1987 (1 page).
JP 61231051 Abstract Only; Oct. 15, 1986 (1 page).
JP 63145325 Abstract Only; Jun. 17, 1988 (1 page).
JP 63179955 Abstract Only; Jul. 23, 1988 (1 page).
JP 8301952 Abstract Only; Nov. 19, 1996 (1 page).
JP 9235329 Abstract Only; Sep. 9, 1997 (1 page).
JP 2000319423 Abstract Only; Nov. 21, 2000 (1 page).
Liu, et al., “Chemically Cross-Linked Polycylooctene: Synthesis, Characterization and Shape Memory Behavior” Macromolecules, (2002), 35, pp. 9868-9874.
Dinger, et al., “High Turnover Numbers with Ruthenium-Based Metathesis Catalysts” Advanced Synthesis Catalysis, vol. 344 (2002) pp. 671-677.
Oh et al., “Dynamic Mechanical Properties of Carbon Black Filled Trans-polyoctenamer Vulcanizates” (Oct. 19, 1985) Abstract Only, 1 page.
Lendlein et al., Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications, Science (2002) 296, pp. 1673-1676.
Nakayama, K., “Properties and Applications of Shape-Memory Polymers”, International Polymer Science and Technology 1991, 18, T/43-48.
Irie, M., Shape Memory Polymers, Cambridge University Press: Cambridge, UK 1998, pp. 203-219.
Boochathum et al., Vulcanization of Cis- and Trans-Polyisoprene and Their Blends: Crystallization Characteristics and Properties, European Polymer Journal, 37 (2001) pp. 429-434.
Boochathum et al., “Vulcanization of Cis- and Trans-Polyisoprene and Their Blends: Cure Characteristics and Crosslink Distribution”, European Polymer Journal 37 (2001) pp. 417-427.
Schwab et al., “Synthesis and Applications of RuCl2(=CHR′)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity”, J. Am. Chem. Soc. (1996) 118, pp. 100-110.
Bielawski et al., “Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands”, Angew. Chem. Int. Ed. (2000) 39, No. 16, pp. 2903-2906.
Calderon et al., “Melting Temperature of trans-Polyoctenamer”, Journal of Polymer Science: Part A-2, vol. 5, (1967), pp. 1283-1292.
Natta et al., “The Monoclinic Structure of Even trans-Polyalkenamers”, European Polymer Journal, vol. 3 (1967) pp. 339-352.
Bassi et al., “The Triclinic Structure of trans-Polyoctenamer”, European Polymer Journal, vol. 4, (1968), pp. 123-132.
Schneider et al., “Crystallinity of trans-Polyoctenamer: Characterization and Influence of Sample History”, Journal of Molecular Catalysis, 46 (1988), pp. 395-403.
Yeh et al., “Radiation-Induced Crosslinking: Effect on Structure of Polyethylene”, Colloid & Polymer Sci. 263 (1985), pp. 109-115.
Fu et al., “Nanoscale Reinforcement of Polyhedral Oligomeric Silsesquioxane (POSS) in Polyurethane Elastomer”, Polymer Int. 49 (2000) pp. 437-440.
Qing Ge and Patrick T. Mather, “Synthesis of Thermoplastic Polyurethanes Bearing Nanostructured Hard Segments: New Shape Memory Polymers” Polymer Program, Institute of Materials Science and Department of Engineering, UCONN, (Jul. 2003), (Abstract, 2 pages).
Du Prez, F. E. et al., “Segmented Networks by Cationic Polymerization: Design and Applications” NATO Sci. Ser., Ser. E, (1999), pp. 75-98.
Goethals et al. “Poly(Vinyl Ethers) as Building Blocks for New Materials” Macromol. Symp., (1998), 132, pp. 57-64.
Kagami et al., “Shape Memory Behaviors of Crosslinked Copolymers Containing Stearyl Acrylate&#x

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Shape memory polymers based on semicrystalline thermoplastic... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Shape memory polymers based on semicrystalline thermoplastic..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Shape memory polymers based on semicrystalline thermoplastic... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3659836

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.