Shape anisotropic metal oxide nanoparticles and synthetic...

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

Reexamination Certificate

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C423S138000, C423S022000, C423S053000, C423S111000, C423S089000, C423S069000, C423S062000, C423S021100, C423S632000, C423S633000, C423S607000, C423S625000, C423S624000, C423S618000, C423S608000, C423S594170, C423S606000, C423S263000, C423S140000, C423S055000, C423S122000, C423S092000, C423S085000, C423S065000, C977S773000, C977S775000, C977S777000, C977S811000

Reexamination Certificate

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07122168

ABSTRACT:
In a metal oxide nanoparticle and a synthetic method thereof, and in particular to maghemite (γ-Fe2O3) nanoparticles usable as a superhigh density magnetic recording substance by having good shape anisotropy and magnetic characteristics, hematite (α-Fe2O3) nanoparticles usable as a precursor to the maghemite or a catalyst, maghemite and hematite-mixed nanoparticles and a synthetic method thereof, the method for synthesizing metal oxide nanoparticles includes forming a reverse micelle solution by adding distilled water, a surfactant and a solvent to metallic salt not less than trivalent, precipitating and separating gel type amorphous metal oxide particles by adding proton scavenger to the reverse micelle solution; adjusting a molar ratio of metal oxide to the surfactant by washing the gel type amorphous metal oxide particles with a polar solvent; and crystallizing metal oxide nanoparticles through heating or reflux after dispersing the gel type amorphous metal oxide particles in a non-polar solvent having a high boiling point.

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patent: 6302940 (2001-10-01), Murray et al.
Victor F. Puntes, et al., “Colloidal Nanocrystal Shape and Size Control: The Case of Cobalt”, Science, vol. 291, Mar. 16, 2002, pp. 2115-2117.
Sang-Jae Park, et al., “Synthesis and Magnetic Studies of Uniform Iron Nanorods and Nanospheres”, J. Am. Chem. Soc., 2000, 122, pp. 8581-8582.
Taeghwan Hyeon, et al., “Synthesis of Highly Crystalline and Monodisperse Maghemite Nanocrystallites without a Size-Selection Process”, J. Am. Chem. Soc., 2001, 123, pp. 12798-12801.
Alexander E. Gash, et al., “Use of Epoxides in the Sol-Gel Synthesis of Porous Iron (III) Oxide Monoliths from Fe(III) Salts”, Chem. Mater., 2001, 12, pp. 999 and 1004.

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