Shallow trench filled with two or more dielectrics for...

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Grooved and refilled with deposited dielectric material

Reexamination Certificate

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C438S618000, C438S675000, C438S740000

Reexamination Certificate

active

06828211

ABSTRACT:

BACKGROUND OF THE INVENTION
(1) Field of the Invention
The present invention relates to methods of fabricating shallow trench isolation and, more particularly, to methods of fabricating shallow trench isolation filled with two or more dielectrics for isolation, coupling, or stress relief in the fabrication of integrated circuits.
(2) Description of the Prior Art
Shallow-trench isolation (STI) is the most popular isolation scheme for advanced CMOS (e.g. 0.25 um and beyond). However, as the spacing of STI is continuously scaled down to <0.15 um, there is significant field penetration into the channel (or body) area from the bias of adjacent source/drain junctions. This is discussed in “Characteristics of CMOS device isolation for the ULSI age”, A. Bryant, W. Hansch, and T. Mii,
International Electron Device Meetings
, p.671, 1994, “Three-dimensional DIBL for shallow-trench isolation MOSFET's”, C. Wang, P. Zhang,
IEEE Trans. on Electron Device
, V.46, No. 1, p.139, 1999, and “The impact of isolation pitch scaling on Vth fluctuation in DRAM cell transistors due to neighboring drain/source electric field penetration”, J. H. Sim, J. K. Lee, and K. Kim,
Symposium of VLSI technology
, p.32-33, 1998. Therefore, such “non-perfect” isolation from STI can result in undesirable effects, such as threshold voltage (Vt) fluctuations, with increasing impact in future technology with smaller STI spacing.
One way to eliminate such field penetration effect, a metallic-shielded STI, was proposed in “High-performance cell transistor design using metallic shield embedded shallow trench isolation (MSE-STI) for Gbit generation DRAM's”, J. H. Sim, J. K. Lee, and K. Kim,
IEEE Transaction on Electron Devices
, Vol. 46, No. 6, p.1212-1217, 1999. In this proposal, a layer of conducting material (e.g. doped poly) fills the isolation trench after liner oxidation. The grounded conducting material in the trench can provide good shielding and therefore can eliminate transistor's narrow-width effect and Vt fluctuations. There is certainly continuous need for better isolation structure and process.
Interestingly, such field penetration effect due to “non-perfect” STI may also be utilized for forming vertical resistors, FETs, and circuits as disclosed in co-pending U.S. patent applications Ser. No. 10/268,465 filed Oct. 10, 2002 to the same inventor. Thus, the coupling effect through STI may also be useful if the coupling through STI is enhanced.
Furthermore, the effect of stress in the active area is discussed in “New mechanical reliability issues for deep-submicron devices”, H. Miura and S. Ikeda,
Symposium of manufacturing technology workshop
, Taiwan, p.140-147, 1998. It is desired to control this stress, especially as it relates to isolation formation. Other related literature includes co-pending U.S. patent application Ser. No. 10/444,874 (TSMC-02-161), “Carrier mobility enhancement in strained Si-on-insulator fabricated by wafer bonding” by L. J. Huang et al,
Symposium VLSI Tech., Dig. Tech. Papers
, Kyoto, Japan, p. 57-58, 2001; “Fabrication and analysis of deep sub-micron strained-Si n-MOSFETs”, by K. Rim et al,
IEEE Trans. Electron Dev
., vol. 47, no. 7, p. 1406-1415, July 2000; “Strained Si surface channel MOSFETs for high performance CMOS technology”, by K. Rim, ISSCC, paper #7.3, p. 116-117, 2001; “Carrier mobility and process stability of strained Si n- and p-MOSFETs on SiGe virtual substrates”, by M. T. Currie et al,
J. Vacuum Science Technology B
, vol. 19, no. 6, p.2268, November/December 2001; “Enhanced performance in sub-100 nm CMOSFETs using strained epitaxial Silicon-Germanium”, by Y. C. Yeo et al,
IEDM
, p. 753, 2000; “SiGe HBT technology: a new contender for Si-based RF and microwave circuit applications”, by J. D. Cressler,
IEEE Trans. Microwave and Techniques
, V. 46, No. 5, p.572-589. Related patents include U.S. Pat. No. 6,297,128 to H. S. Kim et al and U.S. Pat. No. 6,037,237 to M. H. Park et al.
U.S. Pat. No. 6,074,909 to Gruening shows a STI and a vertical transistor process. U.S. Pat. No. 6,255,176B1 to Kim et al shows a STI with a high dielectric constant material. U.S. Pat. No. 6,194,283B1 to Gardner et al discloses a low dielectric constant spacer layer in a STI process. U.S. Pat. No. 5,742,091 to Hebert shows a low dielectric constant material as a liner or as a fill layer in a STI process.
SUMMARY OF THE INVENTION
According, it is an object of the invention that shallow trench isolation regions on the same chip are filled with two or more different dielectric materials.
It is another object of the invention that one shallow trench is filled with a low dielectric constant (k) material for isolation and another shallow trench be filled with a high k material for coupling on the same chip.
Another object of the invention is to provide a method for fabricating shallow trenches filled with two or more different dielectric materials.
Yet another object is to provide a method for fabricating shallow trenches filled with two or more different materials.
A further object of the invention is to provide a method of fabricating a capacitor structure formed by a shallow trench filled with a high k material.
A still further object is to provide a method of fabricating a vertical transistor formed by a shallow trench filled with a high k material.
Yet another object is to provide a method for controlling stress in the silicon active area of an integrated circuit by filling shallow trenches with dielectrics having different thermal expansion coefficients.
In accordance with the objects of this invention, a method for forming shallow trenches having different trench fill materials is achieved. A stop layer is provided on a substrate. A plurality of trenches is etched through the stop layer and into the substrate. A first layer is deposited over the stop layer and filling said trenches. The first layer is planarized to the stop layer leaving the first layer within the trenches. The first layer is removed from a subset of the trenches. A second layer is deposited over the stop layer and within the subset of trenches and planarized to the stop layer leaving the second layer within the subset of trenches to complete fabrication of shallow trenches having different trench fill materials. The trench fill materials may be dielectric layers having different dielectric constants or they may be a dielectric layer and a conducting layer. The method can be extended to provide three or more different trench fill materials.
Also in accordance with the objects of the invention, a method for fabricating a n+ to n+ capacitor is achieved. A stop layer is provided on a substrate. A plurality of trenches is etched through the stop layer and into the substrate. A first layer is deposited over the stop layer and filling the trenches wherein the first layer comprises a dielectric material having a first dielectric constant. The first layer is planarized to the stop layer leaving the first layer within the trenches. The first layer is removed from a subset of the trenches. A second layer is deposited over the stop layer and within the subset of trenches wherein the second layer comprises a dielectric material having a second dielectric constant higher than the first dielectric constant. The second layer is planarized to the stop layer leaving the second layer within the subset of trenches. N+ junctions are formed on either side of one of the subset of trenches wherein the trench forms a capacitor dielectric of the n+ to n+ capacitor. A p+ to p+ capacitor can be formed in a similar way within an n-well.
Also in accordance with the objects of the invention, a method for fabricating a vertical MOSFET is provided. A deep n-well is formed within a substrate. A stop layer is provided on the substrate. A plurality of trenches is etched through the stop layer and into the substrate. A first layer is deposited over the stop layer and filling the trenches wherein the first layer comprises a dielectric material having a first dielectric constant. The first layer

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