Separation process for methyl acetate hydrolysis and...

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – With means applying electromagnetic wave energy or...

Reexamination Certificate

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C422S198000, C422S234000, C422S235000, C202S161000, C203S029000, C203SDIG016

Reexamination Certificate

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07862783

ABSTRACT:
A separation system for a methyl acetate hydrolysis is provided. The separation system comprises a reactive distillation system, a reflux system, a first separation system and a second separation. The reactive distillation system allows the hydrolysis of a methyl acetate solution to generate a first mixture and a second mixture. The reflux system is packed with a heterogeneous catalyst and coupled to the reactive distillation system, which refluxes the first mixture to the reactive distillation system. The first separation system is coupled to the reactive distillation system, which directs the second mixture thereinto so as to isolate an acetic acid and a third mixture therefrom. The second separation system is coupled to the first separation system, which directs the third mixture thereintio so as to separate a methanol therefrom. The methyl acetate feeding system is coupled to, one of the reactive distillation system and the reflux system, which feeds the methyl acetate solution thereinto.

REFERENCES:
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patent: 5770770 (1998-06-01), Kim et al.
patent: 2002/0183549 (2002-12-01), Lee
patent: 2006/0128991 (2006-06-01), Michl et al.
Han, S. J., Y. Jin and Z. Q. Yu. “Application of a Fluidized Reaction-Distillation Column for Hydrolysis of Methyl Acetate”,Chem. Eng. Journal66 (1997), pp. 227-230.
Fuchigami, Yoshio. “Hydrolysis of Methyl Acetate in Distillation Column Packed with Reactive Packing of Ion Exchange Resin”,Journal of Chem. Eng. of Japan, vol. 23, No. 3 (1990), pp. 354-359.

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