Separation of zirconium and uranium

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ivb metal

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423 9, C01G 2500

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active

043812872

ABSTRACT:
Zirconium- and uranium-containing hydrocarbon-amine solutions are treated for separation of zirconium and uranium by means of a process comprising: (1) selective stripping of zirconium with an aqueous chloride solution, and (2) scrubbing the resulting aqueous solution with chloride-loaded hydrocarbon-amine solution to selectively remove uranium, thereby yielding an aqueous zirconium solution of low uranium content.

REFERENCES:
patent: 2877250 (1959-03-01), Brown et al.
patent: 2923607 (1960-02-01), Peppard
patent: 3006719 (1961-10-01), Miller
patent: 3178256 (1965-04-01), Moore
Merritt, Robert C., "The Extractive Metallurgy of Uranium", Colorado School of Mines Research Institute, 1971, pp. 194-201.
Coleman, C. F. et al., "Solvent Extraction with Alkyl Amines", in Industrial and Engineering Chemistry, vol. 50, No. 12., Dec. 58, pp. 1756-1762.

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