Separation of unsaturated hydrocarbons by extractive distillatio

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 58, 203 63, 585809, 585860, 585865, B01D 340

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active

051548020

ABSTRACT:
The separation of alkadienes from close-boiling alkenes by extractive distillation employs as solvent either N-(.beta.-mercaptoethyl)-2-pyrrolidone alone, or a mixture of N-(.beta.-mercaptoethyl)-2-pyrrolidone and either N-methyl-2-pyrrolidone or cyclohexanol, or a mixture of cyclohexanol and tetraethylene glycol. The separation of cycloalkadines from close-boiling alkadienes by extractive distillation employs N-(.beta.-mercaptoethyl)-2-pyrrolidone as solvent.

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