Separation of the isotopes of boron by chemical exchange reactio

Chemistry of inorganic compounds – Boron or compound thereof – Binary compound

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423 7, 423 8, 423298, 423276, 210151, 210682, 252135, 252517, 2041572, C01B 3506

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active

054198879

ABSTRACT:
The isotopes of boron, .sup.10 B and .sup.11 B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF.sub.3 and a liquid BF.sub.3 . donor molecular addition complex formed between BF.sub.3 gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone.

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patent: 5265135 (1993-11-01), Impink, Jr. et al.
Palko, A. A., The Chemical Separation of Boron Isotopesi, ORNL-5418, Jun. 1978, pp. 1-79.
Excerpts from Proceedings of the International Symposium on Isotope Separation (Amsterdam, Apr. 23-27, 1957), ed. Kistemaker et al., Chap. 11-14, pp. 178-209.
Merriman, J. R., J. H. Pashley, N. W. Snow, Engineering-Scale Studies of Boron Isotope Separation, Report No. K-1653 from Union Carbide Corporation, Nuclear Division; 1966, pp. 1-124.

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