Separation of phenol, cyclohexanone, and cyclohexylbenzene conta

Distillation: processes – separatory – Adding material to distilland except water or steam per se – Organic compound

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203 51, 260586P, 260621C, 260621A, B01D 340, C07C 3904, C07C 4930

Patent

active

040199657

ABSTRACT:
Phenol, cyclohexanone, and cyclohexylbenzene containing mixtures are extractively distilled to provide overhead of cyclohexylbenzene and cyclohexanone and a kettle product substantially free of cyclohexylbenzene by employing a dialkyl and/or a dicycloalkyl phthalate. Co-agents or modifiers, e.g., sulfolane, polyalkylene glycols, etc., are advantageously used in some instances.

REFERENCES:
patent: 2171795 (1939-09-01), Kautter
patent: 2762760 (1956-09-01), Walker
patent: 2986583 (1961-05-01), Robbers et al.
patent: 3169101 (1965-02-01), Berthoux
patent: 3284320 (1966-11-01), Fannin et al.
patent: 3492362 (1970-01-01), Nettesheim
patent: 3630855 (1971-12-01), Turbin

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