Separation of nickel and cobalt from sulfate solutions by solven

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Iron group metal

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423DIG14, 75101BE, 75119, 210688, C01G 5100, C01G 5300

Patent

active

049005227

ABSTRACT:
Sulfate solutions containing nickel and cobalt ions are treated by solvent extraction to provide a nickel raffinate with a high Ni:Co ratio and a cobalt raffinate with a high Co:Ni ratio and with low recycle of cobalt by treating the solution with a cobalt extractant to provide a nickel raffinate of high Ni:Co ratio and a loaded extractant, acid stripping the loaded extractant to provide a cobalt sulfate solution containing some nickel and a regenerated cobalt extractant, treating the cobalt sulfate solution with a nickel extractant to provide a cobalt raffinate with a high Co:Ni ratio and acid stripping the loaded nickel extractant to regenerate the extractant and to provide a recyclable sulfate solution containing only a small proportion of the original cobalt.

REFERENCES:
patent: 4196076 (1980-04-01), Fujimoto et al.
patent: 4528167 (1985-07-01), Preston

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