Separation of n-hexyl acetate from n-hexyl alcohol by extractive

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 57, 203 60, 203 64, 560248, B01D 340, C07C 6748

Patent

active

046953507

ABSTRACT:
n-Hexyl acetate cannot be completely removed from n-hexyl acetate- n-hexyl alcohol- water mixtures by distillation because of the presence of the minimum ternary azeotrope. n-Hexyl acetate can be readily removed from mixtures containing it, n-hexyl alcohol and water by using extractive distillation in which the extractive distillation agent is dimethylsulfoxide or a mixture of DMSO with a higher boiling organic compound. Typical examples of effective agents are DMSO; DMSO and tetraethylene glycol; DMSO, dimethylformamide and hexylene glycol.

REFERENCES:
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patent: 2489619 (1949-11-01), Carlson et al.
patent: 2575285 (1951-11-01), Carlson et al.
patent: 4379028 (1983-04-01), Berg et al.
patent: 4469905 (1984-09-01), Inwood et al.
patent: 4525245 (1985-06-01), Berg et al.

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