Separation of m-xylene from o-xylene by extractive distillation

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 57, 203 60, 203 61, 203 64, 203 65, 585805, 585866, B01D 340, C07C 708

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active

047387556

ABSTRACT:
m-Xylene is difficult to separate from o-xylene by conventional rectification or distillation because of the close proximity of their boiling points. m-Xylene can be readily separated from o-xylene by using extractive distillation in which the extractive agent is ethyl-2-hydroxybenzoate; methyl benzoate plus benzophenone; methyl benzoate, butyl benzoate and dimethylsulfoxide.

REFERENCES:
patent: 2494274 (1950-01-01), Woerner
patent: 2721170 (1955-10-01), Johnson
patent: 2763604 (1956-09-01), Dorsey et al.
patent: 3116224 (1963-12-01), Bailey
patent: 4488937 (1984-12-01), Berg et al.

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