Separation of m-xylene from o-xylene by extractive distillation

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 58, 203 60, 203 63, 203 69, 203 56, 203 57, 203 61, 203 62, 203 64, 203 65, 585805, B01D 340, C07C 708

Patent

active

044889372

ABSTRACT:
m-Xylene is difficult to separate from o-xylene by conventional rectification or distillation because of the close proximity of their boiling points. m-Xylene can be readily separated from o-xylene by using extractive distillation in which the extractive agent is ethyl-2-hydroxybenzoate; propoxypropanol puls 1,4-butanediol; sulfolane plus dimethylsulfoxide plus ethyl benzoate.

REFERENCES:
patent: 2456561 (1948-12-01), Lake et al.
patent: 2721170 (1955-10-01), Johnson
patent: 2738372 (1956-03-01), Talbot
patent: 2880253 (1959-03-01), Jezl et al.
patent: 2957811 (1960-10-01), Geiser
patent: 3116224 (1963-12-01), Bailey, Jr.
patent: 4024028 (1977-05-01), Haskell

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