Separation of hydrogen isotopes

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204163HE, 423 2, C01B 332, B01D 5900

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active

043990118

ABSTRACT:
Isotopes of hydrogen are separated by reacting a normal alkane, its deuterated form, atomic bromine, a deactivating gas, and a isotopically selective vibrational sensitizer gas selected from the class consisting of carbon dioxide, carbon monoxide, nitrogen, and mixtures thereof and separating the products which are enriched in deuterium.

REFERENCES:
patent: 4000420 (1976-12-01), Harris
patent: 4025408 (1977-05-01), Marling
patent: 4081339 (1978-03-01), Benson
patent: 4097384 (1978-06-01), Coleman et al.
Mayer et al., "Isotope Separation With the cw Hydrogen Fluoride Laser," Aied Physics Letters 12-12-70, pp. 516-519.
Hsu et al. "Deuterium Enrichment by CW CO.sub.2 Laser-induced Reaction of Methane," Applied Physics Lett. 33(11) pp. 915-917.
Chien et al., J. Phys. Chem. 80:13, 1405 (1976).
Mayer et al., App. Phys. Lett. 17, 516 (1970).
Manuccia et al. J. Chem. Phys. 68:5 (1978).

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