Separation of hydrogen from hydrocarbons utilizing zeolitic...

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Hydrogen component

Reexamination Certificate

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C423S210000, C423S245100, C423S648100, C423S700000, C423S701000, C423S702000, C423S704000, C423S705000, C423S706000, C423S708000, C502S400000, C502S401000, C095S043000, C095S045000, C095S055000, C095S090000, C095S141000, C095S143000, C095S144000, C095S145000, C095S273000, C095S274000, C095S902000

Reexamination Certificate

active

08071063

ABSTRACT:
The present invention relates to the selective separation of hydrogen (“H2”) hydrocarbons in streams containing both hydrogen and hydrocarbons (e.g. methane, ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in either a pressure swing adsorption process, a temperature swing adsorption process, or a membrane separations process to separate hydrogen from hydrocarbons present in hydrogen production streams or petrochemical/petroleum refining product streams and intermediate streams.

REFERENCES:
patent: 3885927 (1975-05-01), Sherman et al.
patent: 4775396 (1988-10-01), Rastelli et al.
patent: 4857078 (1989-08-01), Watler
patent: 4869883 (1989-09-01), Thorogood et al.
patent: 5171333 (1992-12-01), Maurer
patent: 5642630 (1997-07-01), Abdelmalek et al.
patent: 5726118 (1998-03-01), Ivey et al.
patent: 5753011 (1998-05-01), Sircar et al.
patent: 6011192 (2000-01-01), Baker et al.
patent: 6531569 (2003-03-01), Tachiki et al.
patent: 6617467 (2003-09-01), Müller et al.
patent: 6624318 (2003-09-01), Müller et al.
patent: 6893564 (2005-05-01), Mueller et al.
patent: 6929679 (2005-08-01), Muller et al.
patent: 6930193 (2005-08-01), Yaghi et al.
patent: 7056482 (2006-06-01), Hakka et al.
patent: 7078235 (2006-07-01), Spencer et al.
patent: 7196210 (2007-03-01), Yaghi et al.
patent: 7202385 (2007-04-01), Mueller et al.
patent: 2002/0104435 (2002-08-01), Baker et al.
patent: 2003/0004364 (2003-01-01), Yaghi et al.
patent: 2003/0078311 (2003-04-01), Muller et al.
patent: 2003/0148165 (2003-08-01), Muller et al.
patent: 2003/0222023 (2003-12-01), Mueller et al.
patent: 2004/0225134 (2004-11-01), Yaghi et al.
patent: 2004/0249189 (2004-12-01), Mueller et al.
patent: 2004/0265670 (2004-12-01), Muller et al.
patent: 2005/0004404 (2005-01-01), Muller et al.
patent: 2005/0124819 (2005-06-01), Yaghi et al.
patent: 2005/0154222 (2005-07-01), Muller et al.
patent: 2005/0192175 (2005-09-01), Yaghi et al.
patent: 2006/0079725 (2006-04-01), Li et al.
patent: 2006/0135824 (2006-06-01), Mueller et al.
patent: 2006/0154807 (2006-07-01), Yaghi et al.
patent: 2006/0185388 (2006-08-01), Muller et al.
patent: 2006/0252641 (2006-11-01), Yaghi et al.
patent: 2007/0068389 (2007-03-01), Yaghi
patent: 2007/0202038 (2007-08-01), Yaghi et al.
patent: 2008/0184883 (2008-08-01), Zhou et al.
patent: 2926524 (1979-06-01), None
patent: 0 700 708 (1996-03-01), None
patent: 1 148 025 (2001-10-01), None
patent: 0 790 263 (2002-02-01), None
patent: 1 674 555 (2005-12-01), None
patent: 1 383 775 (2006-08-01), None
patent: WO 02/088148 (2002-11-01), None
patent: WO 03/035717 (2003-05-01), None
patent: WO 03/064030 (2003-08-01), None
patent: WO 03/101975 (2003-12-01), None
patent: WO 03/102000 (2003-12-01), None
patent: WO 2004/037895 (2004-05-01), None
patent: WO2004/101575 (2004-11-01), None
patent: WO 2005/003069 (2005-01-01), None
patent: WO 2005/003622 (2005-01-01), None
patent: WO 2005/068474 (2005-07-01), None
patent: WO 2006/028479 (2006-03-01), None
patent: WO 2006/047423 (2006-05-01), None
patent: WO 2006/050898 (2006-05-01), None
patent: WO 2006/089908 (2006-08-01), None
patent: WO 2006/110740 (2006-10-01), None
patent: WO 2007/038508 (2007-04-01), None
patent: WO 2007/101241 (2007-09-01), None
Hideki Hayashi, Adrien P. Cote, Hiroyasu Furukawa, Michael O'Keeffe, Omar M. Yaghi, “Zeolite A imidazolate frameworks,”Nature Materials, vol. 6, Jul. 2007, pp. 501-506.
Rahul Banerjee, Anh Phan, Bo Wang, Carolyn Knobler, Hiroyasu Furukawa, Michael O'Keefe, Omar M. Yaghi, “High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application of CO2 Capture,” Science, vol. 319, Feb. 15, 2008, pp. 939-943.
Kyo Sung Park et al.; “Exceptional Chemical and thermal stability of zeolitic imidazolate frameworks,” PNAS, Jul. 5, 2006, vol. 103, No. 27, pp. 10186-10191.
Yun-Qi Tian et al.; “The Silica-Like Extended Polymorphism of Cobalt (II) Imidazolate Three-Dimensional Frameworks: X-ray Single Crystal Structures and Magnetic Properties,” Chem. Eur. J. 2003, 9, pp. 5673-5685.
Yun-Qi Tian et al.; “[Co5(im)10•2MB]•: A Metal-Organic Open-Framework with Zeolite-Like Topology,” Angew. Chem. Int. Ed. 2002, 41, No. 8, pp. 1384-1386.
Xiao-Chun Huang et al., “Ligand-Directed Strategy for Zeolite-Type Metal-Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies,” Angew. Chem. Int. Ed. 2006, 45, pp. 1557-1559.
Ziaochun Huang et al.; “[Zn(bim)x]•(H2O)1.67: A metal-organic open-framework with sodalite topology”; Chinese Science Bulletin, vol. 48, No. 15, Aug. 2003, pp. 1531-1534.
Yun-Qi Tian et al.; “Design and Generation of Extended Zeolitic Metal-Organic Frameworks (ZMOFs): Syntheis and Crystal Structures of Zinc(ii) Imidazolate Polymers with Zeolitic Topologies”; Chem. Eur. J., 2007, 13, pp. 4146-4154.
Yun-Qi Tian et al.; “[CoIICu12(Im)4]∞:A Layered Bimetallic Imidazolate Polymer, the First Hydridized Cobalt (ii) Imidazolate,” Z.Anorg. Allg. Chem., 2004, 630, pp. 1371-1373.
Yun-Qi Tian et al., “Determination of the Solvothermal Synthesis Mechanism of Metal Imidazolates by X-ray Single-Crystal Studies of a Photoluminescent Cadmium(II) Imidazolate and Its Imtermediate Involving Piperazine,” Eur. J. Inorg. Chem., 2004, pp. 1039-1044.
Zhong-Lin Lu et al.; “Synthesis and crystal structure of an imidazolate-bridged dicoppertris(2-aminoethyl)amine complex”; Transition Met. Chem., 22, 1997, pp. 549-552.
Yun-Qi Tian et al.; “Two Polymorphs of Cobalt(II) Imidazolate Polymers Synthesized Solvothermally by Using One Organic TemplateN,N-Dimethylacetamide”; Inorg. Chem. 2004, 43, pp. 4631-4635.
Xiao-Chun Huang, Jie-Peng Zhang, Xiao-Ming Chen; “One-Dimensional Supramolecular Isomerism of Copper(I) and Silver(I) Imidazolates Based on theLigand Orientations,” Crystal Growth & Design, 2006, vol. 6, No. 5, pp. 1194-1198.
Yunling Liu, Victor CH. Kravtsov, Randy Larsen, Mohamed Eddaoudi; “Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities”; Chem. Commun., 2006, pp. 1488-1490.
Philip L. Llewellyn et al.; “How Hydration Drastically Improves Adsorption Selectivity for CO2over CH4 in the Flexible Chromium Terephthlate MIL-53”; Angew. Chem. Int. Ed., 2006, 45, pp. 7751-7754.
Atsushi Kondo et al.; “Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2Molecules”; Nano Letters, 2006, vol. 6, No. 11, pp. 2581-2584.
Katharine Sanderson, “Space Invaders,” news feature in Nature, vol. 448, Aug. 16, 2007, pp. 746-748.

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