Separation of glycerine from bis(hydroxymethyl)tetrahydrofuran b

Distillation: processes – separatory – Adding material to distilland except water or steam per se – Organic compound

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203 60, 203 68, 203 69, 203 70, 547502, 568869, B01D 336, C07C 3122, C07D30706

Patent

active

054219655

ABSTRACT:
Glycerine is difficult to separate from bis(hydroxymethyl)tetrahydrofuran by conventional distillation or rectification because of the proximity of their boiling points. Glycerine can be readily separated from bis(hydroxymethyl)tetrahydrofuran by azeotropic distillation. Effective agents are m-xylene, beta-pinene and dicyclopentadiene.

REFERENCES:
patent: 2993912 (1961-07-01), Dunlop
patent: 3040062 (1962-06-01), Hales
patent: 4655879 (1987-04-01), Brockmann et al.
patent: 4975158 (1990-12-01), Berg
patent: 4980033 (1990-12-01), Berg
patent: 5190622 (1993-03-01), Berg
patent: 5198077 (1993-03-01), Berg

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