Gas separation: processes – Solid sorption – Including reduction of pressure
Patent
1996-07-15
1998-08-11
Spitzer, Robert
Gas separation: processes
Solid sorption
Including reduction of pressure
95102, 95103, 95105, 95139, 95143, B01D 53047
Patent
active
057922390
ABSTRACT:
A natural gas feed stream containing significant quantities of nitrogen and/or carbon dioxide can be increased to a content of greater than 95 percent by volume of natural gas, and preferably greater than about 98 percent, by passing the natural gas feed stream sequentially through three adsorbent beds that are cycled through seven phases comprising: an adsorption phase to adsorb a first gas, a first depressurization phase to remove feed gas from the voids in the adsorbent bed, a recycle phase to remove a second gas from the adsorbent by the passage of a second depressurization gas therethrough and to produce a recycle gas, a second depressurization phase to reduce the adsorbent bed pressure to about ambient and to produce the second depressurization gas, an evacuation phase where the pressure in the adsorbent is further reduced and an enriched primary gas product stream recovered, a pressurization phase where the pressure in the adsorbent bed is increased using secondary product gas from a bed in an adsorption phase, and further pressurizing the adsorbent bed in a pressurization phase by the flow of the recycle gas and feed gas into the adsorbent bed. Various gases can be separated using this process. Nitrogen can be removed from natural gas (adsorbed gas) and carbon dioxide (adsorbed gas) can be removed from natural gas.
REFERENCES:
patent: 3085379 (1963-04-01), Kiyonaga et al.
patent: 3101261 (1963-08-01), Skarstrom
patent: 3141748 (1964-07-01), Hoke et al.
patent: 3246449 (1966-04-01), Stern et al.
patent: 3324626 (1967-06-01), Dresser et al.
patent: 3350080 (1967-10-01), Garwin
patent: 3636679 (1972-01-01), Batta
patent: 3683589 (1972-08-01), Seitz et al.
patent: 3751878 (1973-08-01), Collins
patent: 3797201 (1974-03-01), Tamura
patent: 3838553 (1974-10-01), Doherty
patent: 3944400 (1976-03-01), Bird
patent: 4077779 (1978-03-01), Sircar et al.
patent: 4077780 (1978-03-01), Doshi
patent: 4171207 (1979-10-01), Sircar
patent: 4305734 (1981-12-01), McGill
patent: 4444572 (1984-04-01), Avon et al.
patent: 4512780 (1985-04-01), Fuderer
patent: 4529412 (1985-07-01), Hayashi et al.
patent: 4539020 (1985-09-01), Sakuraya et al.
patent: 4578089 (1986-03-01), Richter et al.
patent: 4581044 (1986-04-01), Uno et al.
patent: 4599094 (1986-07-01), Werner et al.
patent: 4661125 (1987-04-01), Haruna et al.
patent: 4666468 (1987-05-01), Wu
patent: 4675030 (1987-06-01), Czarnecki
patent: 4687498 (1987-08-01), Maclean et al.
patent: 4689062 (1987-08-01), Maclean et al.
patent: 4690695 (1987-09-01), Doshi
patent: 4701187 (1987-10-01), Choe et al.
patent: 4705541 (1987-11-01), Sircar
patent: 4711645 (1987-12-01), Kumar
patent: 4717407 (1988-01-01), Choe et al.
patent: 4732577 (1988-03-01), Koizumi et al.
patent: 4750925 (1988-06-01), Maclean et al.
patent: 4752311 (1988-06-01), Maclean et al.
patent: 4765804 (1988-08-01), Lloyd-Williams et al.
patent: 4770676 (1988-09-01), Sircar et al.
patent: 4784672 (1988-11-01), Sircar
patent: 4790858 (1988-12-01), Sircar
patent: 4813977 (1989-03-01), Schmidt et al.
patent: 4813980 (1989-03-01), Sircar
patent: 4816039 (1989-03-01), Krishnamurthy et al.
patent: 4836833 (1989-06-01), Nicholas et al.
patent: 4846851 (1989-07-01), Guro et al.
patent: 4861361 (1989-08-01), Jain et al.
patent: 4863492 (1989-09-01), Doshi et al.
patent: 4869894 (1989-09-01), Wang et al.
patent: 4892565 (1990-01-01), Schmidt et al.
patent: 4913709 (1990-04-01), Kumar
patent: 4914218 (1990-04-01), Kumar et al.
patent: 4915711 (1990-04-01), Kumar
patent: 5004482 (1991-04-01), Haas et al.
patent: 5006132 (1991-04-01), DiMartino, Sr. et al.
patent: 5013334 (1991-05-01), Maurer
patent: 5015272 (1991-05-01), Okada et al.
patent: 5026406 (1991-06-01), Kumar
patent: 5064446 (1991-11-01), Kusuki et al.
patent: 5080694 (1992-01-01), Knoblauch et al.
patent: 5089048 (1992-02-01), Knoblauch et al.
patent: 5112590 (1992-05-01), Krishnamurthy et al.
patent: 5133785 (1992-07-01), Kumar et al.
patent: 5156656 (1992-10-01), Parker et al.
patent: 5171333 (1992-12-01), Maurer
patent: 5174796 (1992-12-01), Davis et al.
patent: 5207806 (1993-05-01), Lagree et al.
patent: 5224350 (1993-07-01), Mehra
patent: 5226931 (1993-07-01), Combier
patent: 5232473 (1993-08-01), Karpoor et al.
patent: 5234472 (1993-08-01), Krishnamurthy et al.
patent: 5248322 (1993-09-01), Kumar
patent: 5254154 (1993-10-01), Gauthier et al.
patent: 5332424 (1994-07-01), Rao et al.
patent: 5344480 (1994-09-01), Schulte et al.
patent: 5354346 (1994-10-01), Kumar
patent: 5354547 (1994-10-01), Rao et al.
patent: 5382280 (1995-01-01), Choe et al.
patent: 5411721 (1995-05-01), Doshi et al.
patent: 5507856 (1996-04-01), Rao et al.
patent: 5536300 (1996-07-01), Reinhold, III et al.
patent: 5542966 (1996-08-01), D'Amico et al.
patent: 5565018 (1996-10-01), Baksh et al.
C. Tannehill et al; Nitrogen Removal Costs Vary By Concentration; The American Oil & Gas Reporter; pp. 54-61; May 1994.
R. J. Buras et al; Nitrogen Rejection with Pressure Swing Adsorption: Principles, Design, and Remote Control using an Expert System -- Univ. of Oklahoma Laurance Reid Gas Conf.; pp. 93-101; Feb. 28 -Mar. 2, 1994.
T.C. Frankiewicz et al; Methane/Nitrogen Gas Separation over the Zeolite Clinoptilolite by the Selective Adsorption of Nigrogen; American Chemical Society, pp. 213-233; 1983.
L.H. Shendalman et al; A Study of Heatless Adsorption in the Model System CO.sub.2 in He, I; Chemical Engineering Science, vol. 27, pp. 1449-1458; 1972.
J.E. Mitchell et al; Study of Heatless Adsorption in the Model System CO.sub.2 in He: Part II, Esso Research and Engineering Co.; pp. 25-32 1973.
H. C. Cheng et al; Recovery and Purification of Light Gases by Pressure Swing Absorption;l American Chemical Sociey; pp. 195-211; 1983.
D.E. Kowler et al; The Optimal Control of a Periodic Adsorber; Univ. of Michigan pp. 1207-1219; Nov. 1972.
P.H. Turnock et al; Separation of Nitrogen and Methane via Periodic Adsorption; Univ. of Michigan; vol.17, No. 2, pp. 335-342; Mar. 1971.
H.C. Cheng et al; Separation of Helium-Methane Mixtures by Pressure Swing Adsorption; AIChE Journal; vol. 31, No. 1, pp. 95-102; Jan. 1985.
M. W. Ackley et al; Kinetic Separation by Pressure Swing Adsorption: Method of Characteristics Model; AIChE Journal; vol. 36; pp. 1229-1238; Aug. 1990.
G. Bird et al; Separation of Nitrogen from Helium Using Pressure-Swing Adsoprtion; Univ. of Bradford, United Kingdom, pp.463-473; 1973.
M.S.A. Baksh et al; A New Composite Sorbent for Methane-Nitrogen Separation by Adsorption; Separation Science and Technology; pp. 845-868; 1990.
Huber Mark
King David R.
Knaebel Kent S.
Reinhold, III Herbert Edward
Nitrotec Corporation
Spitzer Robert
LandOfFree
Separation of gases by pressure swing adsorption does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Separation of gases by pressure swing adsorption, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Separation of gases by pressure swing adsorption will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-384999