Separation of formic acid from dioxane by extractive distillatio

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 57, 203 60, 203 61, 203 62, 203 63, 203 64, 203 65, 549377, 562609, B01D 340, C07C 5144, C07D31912

Patent

active

048062090

ABSTRACT:
Dioxane cannot be completely removed from dioxane and formic acid mixtures by distillation because of the presence of the maximum azeotrope. Dioxane can be readily removed from dioxane - formic acid mixtures by extractive distillation in which the extractive agent is dimethylsulfoxide, either alone or admixed with certain high boiling organic compounds. Examples of effective agents are dimethylsulfoxide; DMSO and octanoic acid; DMSO, neodecanoic acid and methyl salicylate.

REFERENCES:
patent: 2954392 (1960-09-01), Rylander
patent: 4007095 (1977-02-01), Wolf et al.
patent: 4035271 (1977-07-01), Nemtsov et al.
patent: 4285881 (1981-08-01), Yang

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