Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials
Patent
1988-04-25
1989-02-21
Bascomb, Wilbur
Distillation: processes, separatory
Adding material to distilland except water or steam per se
At least two materials
203 56, 203 57, 203 60, 203 61, 203 62, 203 63, 203 64, 203 65, 549377, 562609, B01D 340, C07C 5144, C07D31912
Patent
active
048062090
ABSTRACT:
Dioxane cannot be completely removed from dioxane and formic acid mixtures by distillation because of the presence of the maximum azeotrope. Dioxane can be readily removed from dioxane - formic acid mixtures by extractive distillation in which the extractive agent is dimethylsulfoxide, either alone or admixed with certain high boiling organic compounds. Examples of effective agents are dimethylsulfoxide; DMSO and octanoic acid; DMSO, neodecanoic acid and methyl salicylate.
REFERENCES:
patent: 2954392 (1960-09-01), Rylander
patent: 4007095 (1977-02-01), Wolf et al.
patent: 4035271 (1977-07-01), Nemtsov et al.
patent: 4285881 (1981-08-01), Yang
Berg Lloyd
Szabados Rudolph J.
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