Separation of cyclohexylbenzene-cyclohexanone-phenol-containing

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260586R, 568798, 585807, 585841, 203 32, C07C 4524, C07C 704, C07C 4500

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041698576

ABSTRACT:
A cyclohexylbenzene-cyclohexanone-phenol-containing mixture, for example as obtained by the cleavage of cyclohexylbenzene hydroperoxide, is separated by first catalytically hydrogenating selectively the phenol in the mixture, resulting in a mixture of cyclohexylbenzene, which is unchanged, and cyclohexanone; the thus obtained mixture is subjected to fractional distillation to obtain cyclohexylbenzene which can be returned as to a process for the production of cyclohexylbenzene hydroperoxide, and cyclohexanone.

REFERENCES:
patent: 2857432 (1958-10-01), Joris
patent: 2950320 (1960-08-01), Vandenberg
patent: 4021490 (1977-05-01), Hudson
patent: 4092360 (1978-05-01), Van Peppen et al.
patent: 4115204 (1978-09-01), Murtha et al.
patent: 4120902 (1978-10-01), Wu

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