Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1987-11-16
1989-07-25
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5142
Patent
active
048515736
ABSTRACT:
Citric acid is separated from a fermentation broth by using an adsorbent comprising a water-insoluble macroreticular or gel weakly basic anionic exchange resin possessing tertiary amine functional groups or pyridine functional groups, said anionic exchange resin comprising a cross-linked acrylic or styrene resin matrix. Citric acid is desorbed by water or dilute sulfuric acid. The pH of the feed is maintained below the first ionization constant (pKa.sub.1) of citric acid to maintain selectivity.
REFERENCES:
patent: 4323702 (1982-04-01), Kowabata et al.
Kulprathipanja Santi
Oroskar Anil R.
Priegnitz James W.
Hall Jack H.
Killos Paul J.
McBride Thomas K.
Spears Jr. John F.
UOP
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