Separation of analysis of anions

Liquid purification or separation – Processes – Chromatography

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2101982, B01D 1508

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active

045004315

ABSTRACT:
This invention makes a rapid and accurate anion separation analysis possible by using an electric conductivity detector built in a chromatographic apparatus and a binary composite solution as an eluent. The binary composite solution: borax and an aliphatic acid/an aromatic acid/a saccharic acid/a sugar is used in alkaline regions, while the binary composite solution: a sulphonic acid and boric acid/a monocarboxylic acid is used in acid regions. Over a conventional analysis employing phthalic acid or benzoic acid singly, this analysis has an advantage in capturing a wider variety of anions on chromatograph with high accuracy in more sensitized condition without suffering a hindrance due to noises or peaks having nothing to do with objective anions because the electric conductivity of the eluent itself is very low.

REFERENCES:
"Sodium and Potassium Benzoate and Benzoic Acid as Eluents for Ion Chromatography," D. T. Gjerde and J. S. Fritz, Anal. Chem., vol. 53, No. 14, pp. 2324-2327, (Dec. 1981).
"Single-Column Ion Chromatography for the Determination of Chloride and Sulfate in Steam Condensate and Boiler Feed Water," K. M. Roberts, D. T. Gjerde and J. S. Fritz, Anal. Chem., vol. 53, No. 11, pp. 1691-1695, (Dec. 1981).
"Factors Affecting the Resolution and Detectability of Inorganic Anions by Non-Suppressed Ion Chromatography," J. A. Glatz and J. E. Girard, J. of Chromatographic Sciences, vol. 20, pp. 266-273, (Jun. 1982).
Introduction to Modern Liquid Chromatography by Snyder et al., John Wiley & Sons of New York, p. 425, (1979).
Fundamentals of Chromatography by Cassidy, Interscience Publishers of New York, pp. 312-314, (1957).

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