Separation of acetone from methanol by extractive distillation

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 57, 203 60, 203 62, 203 63, 203 64, 568411, B01D 340, C07C 2984

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active

046209018

ABSTRACT:
Acetone cannot be completely removed from acetone-methanol mixtures by distillation because of the presence of the minimum boiling azeotrope. Acetone can be readily separated from methanol by using extractive distillation in which the extractive agent is dimethylformamide, either alone or admixed with other compounds. Typical examples of effective agents are: dimethylformamide; dimethylformamide and diethylene glycol; dimethyl formamide, glycerine and propylene glycol.

REFERENCES:
patent: 2179991 (1939-11-01), Bright et al.
patent: 3419477 (1968-12-01), Mattia
patent: 4501645 (1985-02-01), Berg et al.
patent: 4543164 (1985-09-01), Berg et al.

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