Separation of 3-methyl-2-butanol from 2-pentanol by azeotropic

Distillation: processes – separatory – Adding material to distilland except water or steam per se – Organic compound

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203 60, 203 63, 203 67, 203 70, 568913, B01D 336, C07C 2982, C07C 31125

Patent

active

054395615

ABSTRACT:
3-Methyl-2-butanol is difficult to separate from 2-pentanol by conventional distillation or rectification because of the proximity of their boiling points. 3-Methyl-2-butanol can be readily separated from 2-pentanol by azeotropic distillation. Effective agents are 2,2-dimethyl butane, ethyl acetate and dioxane.

REFERENCES:
patent: 2483246 (1949-09-01), Stribley
patent: 2551584 (1951-05-01), Carlson et al.
patent: 2552911 (1951-05-01), Steitz
patent: 2575243 (1951-11-01), Carlson et al.
patent: 4969977 (1990-11-01), Berg

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