Separation of 2-pentanone from formic acid by extractive distill

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 56, 203 57, 203 60, 203 61, 203 62, 203 63, 203 64, 203 65, 562609, 568410, B01D 340, C07C 4583, C07C 5302

Patent

active

047939010

ABSTRACT:
2-Pentanone cannot be completely removed from 2-pentanone and formic acid mixtures by distillation because of the presence of the maximum azeotrope. 2-Pentanone can be readily removed from 2-pentanone formic acid mixtures by extractive distillation in which the extractive agent is dimethylsulfoxide, either alone or mixed with certain high boiling organic compounds. Examples of effective agents are dimethylsulfoxide; DMSO and octanoic acid; DMSO, hexanoic acid and isophorone.

REFERENCES:
patent: 2010384 (1935-08-01), van Melsen
patent: 2586929 (1952-02-01), Fleming et al.
patent: 2954392 (1960-09-01), Rylander
patent: 3013954 (1961-12-01), Pacoud et al.
patent: 3228985 (1966-01-01), Carpenter et al.
patent: 3265592 (1966-08-01), van der Weel
patent: 4459178 (1984-07-01), Berg

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