Separation method using an ITQ-29 zeolite material

Mineral oils: processes and products – Fractionation – Adsorption

Reexamination Certificate

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C423S219000, C423S235000, C423S239100, C423S239200

Reexamination Certificate

active

07611623

ABSTRACT:
The invention relates to a method of separating the components of a mixture. The inventive method is characterised in that it comprises the following steps: (a) the bringing into contact of the components of a mixture selected from (i) at least two hydrocarbons, (ii) a mixture containing at least nitrogen and oxygen, and (iii) at least one hydrocarbon and water, with an ITQ-29 zeolite material having a T(IV)/T(III) ratio of greater than 7, whereby T(IV) denotes one or more tetravalent elements and T(III) denotes one or more trivalent elements; (b) preferential adsorption of one or more of the components by the ITQ-29 zeolite material and (c) recovery of one or more of the components, preferably for the separation of hydrocarbon mixtures, such as linear or branched olefins from paraffins.

REFERENCES:
patent: 5292990 (1994-03-01), Kantner et al.
patent: 5365011 (1994-11-01), Ramachandran et al.
patent: 6200366 (2001-03-01), Bülow et al.
patent: 6713041 (2004-03-01), Moscoso et al.
patent: 1 736 441 (2006-12-01), None
Avelino Corma et al., “Supramolecular self-assembled molecules as organic directing agent for synthesis of zeolites”, Nature, vol. 431, pp. 287-290, Sep. 2004.
L. Grace et al., “Recovering Olefins Using Adsorption”, Chemical Engineering, vol. 104, n ° 11, pp. 124-125, Nov. 1997.
Ch. Baerlocher et al., “Atlas of Zeolite Framework Types”, Fifth Revised Edition, published on behalf of the Structure Commission of the International Zeolite Association, pp. 1-19 and pages having ring structures referred to therein, 2001.

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