Separation method

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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Details

2041823, 204130, C25F 700

Patent

active

052250563

ABSTRACT:
A first metal, for example a transition metal such as cobalt, having an insoluble hydroxide is separated from a second metal such as lithium having a soluble hydroxide in an aqueous liquid containing dissolved cations of the metals. The cations are firstly absorbed onto a cation exchange material by electrochemical ion exchange and the second metal then selectively eluted by electrochemical ion exchange under sufficiently high pH conditions, e.g. to 10-13, in a closed loop. Finally, the transition metal is eluted by electrochemical ion exchange under sufficiently low pH conditions, e.g. acidic such as 1-2. The method is applicable to separating trace quantities of Co (e.g. as Co-60) from larger quantities of Li in aqueous solution.

REFERENCES:
patent: 3042597 (1962-07-01), Schumacher
patent: 3484188 (1969-12-01), Schneider
patent: 3533929 (1970-10-01), Evans

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