Separation by rectification of unsaturated carboxylic acids from

Distillation: processes – separatory – Addition of material to distilland to inhibit or prevent... – For inhibiting or preventing a polymerization reaction

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203 37, 203 59, 203DIG21, B01D 300, B01D 5900

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active

057282722

ABSTRACT:
In a process for the separation by rectification of unsaturated carboxylic acids from solvents in which the acids were absorbed after the synthesis reaction, the rectification is briefly interrupted and the rectification column is flushed with a basic solution. The interruption is carried out at regular time intervals. The basic solution used is an aqueous solution of alkali metal and/or alkaline earth metal hydroxide, preferably NaOH, KOH, Ca(OH).sub.2 or their anhydrous oxides; alkaline polar organic solvents as amines or amides can be used, too.

REFERENCES:
patent: 3157693 (1964-11-01), Wheeler et al.
patent: 3470238 (1969-09-01), Asano et al.
patent: 3818079 (1974-06-01), Sato et al.
patent: 3893895 (1975-07-01), Dehnert et al.

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