Separation and purification of ruthenium

Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium

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423 22, C01G 5500

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active

041054423

ABSTRACT:
A process for the separation or purification of ruthenium from solutions thereof comprising conversion of the ruthenium to nitrosylruthenium complex with the ruthenium in the Ru.sup.+2 oxidation state; conversion of the nitrosylruthenium complex to a nitrosylruthenium chlorocomplex and any other platinum group metals to chlorocomplexes; and the removal of the nitrosylruthenium chlorocomplex from solution using a suitable liquid or resin anion exchanger.

REFERENCES:
patent: 2894816 (1959-07-01), Hyman et al.
patent: 4002470 (1977-01-01), Isa et al.
Kraak, "Nuclear Science Absts." vol. 14, Jul. 15, 1960, #12643.
Brown et al., "Journal Applied Chem.," Oct. 1960, pp. 422-428.
Sinitzin et al., "Proceedings of International Solvent Extraction Conference, 1974", Soc. of Chemical Industry, London, 1974, vol. 3, pp. 2703-2713.

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