Separating the chlorination products from the reaction gases obt

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570262, C07C 1710

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active

044567782

ABSTRACT:
The reaction gases from the chlorination of methane and preferably also methyl chloride, after removal of the HCl and drying, are subjected to the steps of partially condensing the dried stream of reaction gases at a pressure of 5-15 bars and at a temperature of 0.degree.-40.degree. C. which condenses the chloroform and the carbon tetrachloride; contacting the gaseous phase of the partially condensed stream of reaction gases in a countercurrent manner with a stream of liquid methyl chloride; recycling the stream of gases discharging from the contacting stream of liquid methyl chloride to the chlorination stage; and fractionating the contacting stream of liquid methyl chloride.

REFERENCES:
patent: 1975727 (1934-10-01), Levine
patent: 3126419 (1964-03-01), Burks et al.
patent: 3848007 (1974-11-01), Forlano
patent: 3980723 (1976-09-01), Riegel
patent: 3988383 (1976-10-01), Huang et al.
patent: 4039597 (1977-08-01), Tsao
Ullmann, "Encyclopadie der Technischen Chemie", 5, 406, 3rd Ed. (1954) TPU6. First Article Titled Methanchlorierung ber den Chem. Werken Huls.

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