Sensitized production of sulfhydryl compounds using ultraviolet

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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Details

204158R, 20415918, 20415922, 2041592, 20415924, 204162R, 260 4237, 260 79, 260830S, C08F 246, B01J 110

Patent

active

040522830

ABSTRACT:
An improved process for production of sulfhydryl-terminated compounds by reaction of an allene compound and hydrogen sulfide is disclosed wherein the reaction is carried out in the presence of ultraviolet light of wavelength substantially above 2600 Angstroms and of an organic photosensitizing reagent to obtain a substantially colorless product of improved purity at an increased reaction rate. The invention also includes polymerization of the crude sulfhydryl-terminated product with an unsaturated compound to prepare sulfhydryl-terminated polythioethers which are useful as chemical intermediates and precursors of elastomeric sealants, such as architectural sealants.

REFERENCES:
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patent: 2411983 (1946-12-01), Vaughan
patent: 2873239 (1959-02-01), Nummy et al.
patent: 3398200 (1968-08-01), Griesbaum et al.
patent: 3412001 (1968-11-01), Edwards
patent: 3488270 (1970-01-01), Griesbaum et al.
patent: 3992274 (1976-11-01), Dannels

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