Semipermeable membranes prepared from polymers containing penden

Gas separation – Means within gas stream for conducting concentrate to collector

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55 68, 55158, B01D 5322

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active

045212244

ABSTRACT:
Semipermeable membranes useful for the separation of gases from a mixture containing at least two fractions into enriched fractions of each, the membrane formed from at least one polymer containing a preponderance of arylene units of the formula ##STR1## where each R is independently a C.sub.1 -C.sub.8 aliphatic or a C.sub.5 -C.sub.7 cycloaliphatic hydrocarbon radical, an aryl radical, an aralkyl radical or an alkaryl radical, each radical being free of a tertiary alpha-carbon atom; each Q is a radical of the formula ##STR2## where R' is a C.sub.1 -C.sub.20 linear or branched hydrocarbon or a nonpolymeric aryl radical; X is a divalent oxygen or sulfur atom or a carbonate group; m is an integer of 0-2; and n is 0-1 with the proviso that n is 1 in at least 10 percent of the arylene units of the polymer. A process is also provided whereby a mixture of gases is separated with the foregoing semipermeable membrane.

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