Bleaching and dyeing; fluid treatment and chemical modification – Dyeing involving animal-derived natural fiber material ,... – Hair dyeing
Reexamination Certificate
2001-12-20
2004-06-08
Mruk, Brian P. (Department: 1751)
Bleaching and dyeing; fluid treatment and chemical modification
Dyeing involving animal-derived natural fiber material ,...
Hair dyeing
C008S407000, C008S414000, C008S426000, C008S435000, C008S454000, C008S455000, C008S462000, C008S463000, C008S466000, C008S578000, C008S581000, C008S632000, C008S678000
Reexamination Certificate
active
06746492
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semipermanent hair dye composition which can uniformly dye hair without coloring the scalp and skin and gives the hair an excellent feel after hair coloring.
2. Description of the Background Art
Semipermanent hair dye compositions that a direct dye is caused to penetrate into hair to color the hair have been known as hair dye compositions. Since the direct dye is great in molecular size, it can not easily penetrate into hair, and so it has involved a problem that it takes a long time to color the hair with such a dye. However, the treatment time is greatly shortened at present with the development of the penetration-enhancing technique with solvents.
However, the skin is colored with more ease than the hair due to the difference in structure between them. Therefore, when a treatment is conducted with a hair dye composition using a direct dye, such a composition has involved a problem that it colors the surface of the scalp at the same time as hair coloring.
Therefore, there has been a demand for development of a semipermanent hair dye composition which can uniformly dye hair without coloring the scalp and skin and gives the hair an excellent feel after hair coloring.
SUMMARY OF THE INVENTION
The present inventors have found that a hydrocarbon oil and polyoxyalkylene-modified dimethyl polysiloxane are used in combination with a direct dye, the above problem can be solved.
According to the present invention, there is thus provided a semipermanent hair dye composition comprising the following components (A), (B) and (C):
(A) a direct dye;
(B) a hydrocarbon oil; and
(C) polyoxyalkylene-modified dimethyl polysiloxane.
The hair dye composition according to the present invention can uniformly dye hair without coloring the scalp and skin and gives the hair a moisturized and smooth feel after hair coloring.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Examples of the direct dye of the component (A) include nitro dyes, anthraquinone dyes and acid dyes, oil-soluble dyes and basic dyes.
Examples of the nitro dyes include 3,4-diaminonitrobenzene, 2,5-diaminonitrobenzene, 2-amino-5-N-&bgr;-hydroxyethylaminonitrobenzene, 2-N-&bgr;-hydroxyethylamino-5-N,N-bis-&bgr;-hydroxyethylaminonitrobenzene, 2-N-methylamino-5-N,N-bis(&bgr;-hydroxy-ethyl)aminonitrobenzene, 2-N-methylamino-5-N-methyl-&bgr;-hydroxyethylaminonitrobenzene, 2-N-&bgr;-hydroxy-ethylamino-5-hydroxynitrobenzene, 3-methoxy-4-N-&bgr;-hydroxyethylaminonitrobenzene, 4-nitro-3-methylaminophenoxyethanol, 2-N-&bgr;-hydroxyethylamino-5-aminonitrobenzene, 2-N-&bgr;-hydroxyethylamino-nitrobenzene, 3-amino-4-N-&bgr;-hydroxyethylaminonitrobenzene, 3-&bgr;-hydroxyethoxy-4-N-&bgr;-hydroxyethylaminonitrobenzene, 2-amino-5-N-methylaminonitrobenzene, 2-amino-3-methylnitrobenzene, 2-N-&bgr;-hydroxyethylamino-5-&bgr;,&ggr;-dihydroxypropoxynitrobenzene, 3-hydroxy-4-N-&bgr;-hydroxyethylaminonitrobenzene, 3-hydroxy-4-aminonitrobenzene, 2,5-N,N′-&bgr;-hydroxyethylaminonitrobenzene, 2-N-methylamino-4-o-&bgr;,&ggr;-dihydroxypropoxynitrobenzene, 2-N-&bgr;-aminoethylamino-5-N,N-bis(&bgr;-hydroxyethyl)aminonitrobenzene, 2-N-&bgr;-aminoethylamino-4-methoxynitrobenzene and 2-N-&bgr;-aminoethylamino-5-&bgr;-hydroxyethoxynitrobenzene.
Examples of the anthraquinone dyes include 1-amino-4-methylaminoanthraquinone and 1,4-diaminoanthraquinone.
Examples of the acid dyes include Acid Red 27, Acid Red 51, Acid Red 18, Acid Red 92, Acid Red 94, Acid Red 52, Pigment Red 57-1, Acid Red 33, Acid Red 87, Acid Violet 9, Food Red 6, Acid Red 26, Food Red 1, Acid Red 88, Acid Orange 7, Acid Red 95, Acid Yellow 23, Food Yellow 3, Acid Yellow 73, Acid Yellow 3, Acid Yellow 40, Acid Yellow 1, Acid Yellow 36, Acid Yellow 11, Food Green 3, Acid Green 25, Solvent Green 7, Acid Green 5, Acid Green 1, Acid Green 3, Food Blue 2, Acid Blue 74, Acid Blue 5, Acid Blue 9, Acid Violet 43, Acid Black 1, Acid Blue 1, Acid Blue 3, Acid Blue 62, Acid Black 52, Acid Brown 13, Acid Green 50, Acid Orange 6, Acid Red 14, Acid Red 35, Acid Red 73, Acid Red 184 and Brilliant Black 1.
Examples of the oil-soluble dyes include Solvent Red 49, Solvent Red 48, Solvent Red 23, Solvent Red 72, Solvent Red 73, Acid yellow 33, Solvent Green 3, Solvent Violet 13, Solvent Red 24, Solvent Orange 7, Solvent Orange 2, Solvent Yellow 5, Solvent Yellow 6 and Solvent Blue 63.
Examples of the basic dyes include Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41, Basic Blue 99, Basic Brown 4, Basic Brown 16, Basic Brown 17, Basic Green 1, Basic Red 2, Basic Red 12, Basic Red 22, Basic Red 51, Basic Red 76, Basic Violet 1, Basic Violet 3, Basic Violet 10, Basic Violet 14, Basic Violet 57, Basic Yellow 87 and Basic Orange 31.
Among these, the acid dyes are preferred, with Acid Yellow 23, Acid Yellow 1, Acid Orange 7, Food Green 3, Acid Green 25, Solvent Green 7, Acid Red 27, Acid Red 92, Acid Red 52, Pigment Red 57-1, Acid Red 33, Food Blue 2, Acid Blue 9, Acid Violet 43 and Acid Black 1 being particularly preferred.
The above-described direct dyes may also be used in any combination thereof, and the content thereof is preferably 0.005 to 5% by weight, particularly 0.01 to 2% by weight in the dye composition according to the present invention.
Examples of the hydrocarbon oil of the component (B) include liquid paraffin, liquid isoparaffin and squalane. The hydrocarbon oils may also be used in any combination thereof, and the content thereof is preferably 0.1 to 20% by weight, more preferably 0.5 to 10% by weight, particularly 1 to 5% by weight in the dye composition according to the present invention from the viewpoints of the inhibitory effect on coloring of the scalp and skin and giving no sticky feel.
The polyoxyalkylene-modified dimethyl polysiloxane of the component (C) is that with a polyoxyalkylene group, preferably a polyoxyethylene group bonded to a main chain of dimethyl polysiloxane, and those having HLB of 1 to 6, particularly 2 to 5 are preferred. Such a polysiloxane may have a polyoxypropylene group in addition to the polyoxyethylene group. Specific examples thereof include Silicone KF6015, KF6017, KF945A and KF353A, KF352A (all, products of Shin-Etsu Chemical Co., Ltd.), SILWET L-720, L-7001 and L-7002 (all, products of Nippon Unicar Co., Ltd.), and Silicone SH-3775 (product of Toray Dow Corning Co., Ltd.). The polyoxyalkylene-modified dimethyl polysiloxanes may also be used in any combination thereof, and the content thereof is preferably 0.001 to 30% by weight, more preferably 0.01 to 10% by weight, particularly 0.1 to 5% by weight in the dye composition according to the present invention from the viewpoints of a feel upon application, stability of the system and rinsing out.
In order to facilitate penetration of a direct dye into hair to improve hair-dyeing ability, an organic solvent selected from a compound represented by the following general formula (1), a compound represented by the following general formula (2), an alkylene carbonate having 2 to 5 carbon atoms and a 5- or 6-membered cyclic lactone which may be substituted by an alkyl, alkenyl, alkoxy or acyl group is preferably contained as a component (D) in the hair dye compositions according to the present invention.
wherein R
1
is a hydrogen atom, a low alkyl group or a group represented by the following formula:
in which R
2
is a hydrogen atom, or a methyl or ethyl group, and R
3
is a single bone or a saturated or unsaturated hydrocarbon group having 1 to 3 carbon atoms,
Y and Z are, independently of each other, a hydrogen atom or a hydroxyl group, and
p, q and r are, independently of each other, an integer of 0 to 5, with the proviso that the cases where p and q are 0, and Z is a hydrogen atom, and where p and q are 0, R
1
is a hydrogen atom, and Z is a hydroxyl group are excluded.
wherein R
4
is a linear or branched alkyl group having 1 to 18 carbon atoms.
Specific examples of the organic solvent of the component (D) include ethanol, 1-propanol, 2-propanol, 1-butanol, isobutanol, ethylene glycol, propylene glycol,
Itou Takashi
Kawai Tetsuya
Elhilo Eisa
Kao Corporation
Mruk Brian P.
Oblon & Spivak, McClelland, Maier & Neustadt P.C.
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