Semiconductor device including a diffusion layer formed...

Active solid-state devices (e.g. – transistors – solid-state diode – Combined with electrical contact or lead – Wire contact – lead – or bond

Reexamination Certificate

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C257S673000, C257S693000, C257S737000, C257S738000, C257S773000, C257S775000, C257S780000

Reexamination Certificate

active

06784557

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention generally relates to a semiconductor device in which a metal wiring is formed so as to be electrically connected to an electrode of a semiconductor element and a part of the metal wiring is used as an external electrode, and a manufacturing method of the same. More particularly, the present invention relates to a semiconductor device having excellent junction reliability between a metal wiring and a ball electrode mounted to an external electrode portion of the metal wiring, and a manufacturing method of the same.
With recent reduction in size and improvement in functions of electronic equipments, an increasing number of input/output (I/O) pins is formed in a semiconductor element, and therefore the pitch of electrodes is reduced.
Especially in a CSP (Chip Size Package) type semiconductor device, electrodes of a semiconductor element are formed by a dry etching method in a diffusion process, whereas wiring electrodes of a substrate on which the semiconductor element is mounted are formed by a wet etching method in an assembling process. Accordingly, the pitch of the wiring electrodes of the substrate on which the semiconductor element is mounted is necessarily greater than that of the electrodes of the semiconductor element. In view of this, a semiconductor device is increasingly developed which deals with the difference between the electrode pitch of the semiconductor element and the wiring-electrode pitch of the substrate. In such a semiconductor device, metal wirings are formed so as to be electrically connected to the respective electrodes of the semiconductor element and a part of each metal wiring is used as an external electrode in order to increase the distance between the external electrodes.
Hereinafter, a conventional semiconductor device will be described with reference to the figures.
FIG. 15A
is a perspective plan view of the conventional semiconductor device.
FIG. 15B
shows an example of the cross-sectional structure taken along line XV—XV of FIG.
15
A.
FIG. 15C
shows another example of the cross-sectional structure taken along line XV—XV of FIG.
15
A.
As shown in
FIGS. 15A and 15B
, electrodes
2
are formed on the surface of a semiconductor element
1
. A passivation film
3
is formed over the surface of the semiconductor element
1
. The passivation film
3
is formed from silicon nitride (SiN) or the like, and has an opening on each electrode
2
. Metal wirings
4
are formed on the passivation film
3
. Each metal wiring
4
is formed from copper (Cu) and electrically connected to a corresponding one of the electrodes
2
. A solder resist film
5
is formed on the metal wirings
4
and the passivation film
3
. The solder resist film
5
has an opening on a portion of each metal wiring
4
which functions as an external electrode (hereinafter, referred to as “external electrode portion”). In order to electrically connect the electrodes
2
formed on the surface of the semiconductor element
1
to wiring electrodes of a substrate (not shown) on which the semiconductor element
1
is mounted, respectively, a ball electrode
6
formed from solder is connected in a molten state to each opening of the solder resist film
3
, that is, to the external electrode portion of each metal wiring
4
.
As shown in
FIG. 15C
, an insulating resin layer
7
may be formed between the semiconductor element
1
having the passivation film
3
thereon and the metal wirings
4
.
In each of the forms of the conventional semiconductor device described above, the wiring electrodes of the substrate on which the semiconductor device is mounted are respectively connected to the metal wirings
4
of Cu formed on the surface of the semiconductor element
1
through the ball electrodes
6
formed from solder. In other words, when the metal wirings
4
are formed from Cu (which is a commonly used metal wiring material), metal junction of Cu (the metal wirings
4
) and solder (the ball electrodes
6
) is formed at the boundary between the metal wiring
4
and the ball electrode
6
.
In the above conventional semiconductor device, however, tin (Sn) contained in solder of the ball electrode
6
diffuses into Cu of the metal wiring
4
to form a Sn—Cu alloy layer. As a result, in the portion of the metal wiring
4
on which the ball electrode
6
is mounted (i.e., the external electrode portion) and the portion near the external electrode portion, the Sn—Cu alloy grows in the most part of the metal wiring
4
. The Sn—Cu alloy is weak and hard. The semiconductor device
1
, the resin film covering the surface of the semiconductor element
1
and the substrate have different thermal expansion coefficients. Accordingly, when the temperature is varied to melt the ball electrodes in the process of mounting the semiconductor device onto the substrate, stresses are generated due to such a difference in thermal expansion coefficient. Accordingly, the Cu—Sn alloy layer formed in the portion of the metal wiring
4
to which the ball electrode
6
is mounted is likely to be broken by the stresses.
SUMMARY OF THE INVENTION
In view of the above problems, it is an object of the present invention to provide a semiconductor device having a metal wiring electrically connected to an electrode of a semiconductor element, and having improved junction reliability between the metal wiring and a ball electrode mounted on an external electrode portion of the metal wiring.
According to one aspect of the present invention, a semiconductor device includes a semiconductor element having an electrode formed on a surface thereof, and a metal wiring formed on the surface of the semiconductor element and electrically connected to the electrode. The metal wiring has an external electrode portion functioning as an external electrode. A thickness of the external electrode portion is greater than that of a non-electrode portion of the metal wiring, i.e., a portion of the metal wiring other than the external electrode portion.
According to the above semiconductor device, in the metal wiring electrically connected to the electrode of the semiconductor element, the thickness of the external electrode portion is greater than that of the non-electrode portion. The external electrode portion of the metal wiring and a wiring electrode of a substrate on which the semiconductor device is mounted may be connected to each other by a ball electrode formed from solder. In this case, when the metal wiring contain, e.g., Cu (which is a commonly used metal wiring material), Sn contained in solder of the ball electrode diffuses into Cu contained in the metal wiring, whereby a Sn—Cu alloy layer having low strength grows in the thickness direction of the external electrode portion. However, since the thickness of the external electrode portion of the metal wiring is greater than that of the non-electrode portion of the metal wiring, this Sn—Cu alloy layer can be prevented from growing through the entire thickness of the external electrode portion. In other words, it is ensured that the thickness of the low-strength Sn—Cu alloy layer in the external electrode portion of the metal wiring is smaller than the thickness of the external electrode portion. Since a part of the external electrode portion is left unchanged into the Sn—Cu alloy layer, the strength of the metal wiring can be maintained even if Cu is used as a metal wiring material. The semiconductor element, the resin film covering the surface of the semiconductor element, and the substrate have different thermal expansion coefficients. Therefore, when the temperature is varied in the process of hardening the resin film covering the surface of the semiconductor element or the process of mounting the semiconductor device onto the substrate, stresses are generated due to such a difference in thermal expansion coefficient. However, the above structure can prevent disconnection of the metal wiring even if such stresses are generated.
According to the above semiconductor device, the thickness of the non-electrode portion of the metal wir

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